{"id":"W3042897262","doi":"10.1139/v01-153","title":"Absolute stereochemistry of the spiroxins","year":2001,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Marine Sponges and Natural Products","field":"Biochemistry, Genetics and Molecular Biology","cited_by":32,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Chromophore; Absolute configuration; Exciton; Circular dichroism; Stereochemistry; Crystallography; Photochemistry; Physics","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002477711,0.0001410601,0.0001545725,0.000245914,0.0003157965,0.0003025552,0.0002105512,0.000227836,0.002907986],"category_scores_gemma":[0.0003120477,0.0001206126,0.000152542,0.0001444683,0.0003372525,0.0002260161,0.0001924309,0.000562128,0.0006529671],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003985509,"about_ca_system_score_gemma":0.0004366136,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003894522,"about_ca_topic_score_gemma":0.0005433021,"domain_scores_codex":[0.9998658,0.00003470277,0.00001439608,0.00003131626,0.00002398428,0.00002976285],"domain_scores_gemma":[0.9996909,0.00004985007,0.00006318791,0.00005186663,0.00009023876,0.0000540261],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002306524,0.00001570825,0.001091374,0.00003727927,0.000004172646,0.0002784492,0.00008031431,0.0002615123,0.9844841,0.005616202,0.0001352655,0.007764956],"study_design_scores_gemma":[0.00004319354,0.0007673876,0.01298352,0.00002707735,0.00002302869,0.001191651,0.0001190319,0.0007966058,0.9694573,0.002695826,0.0118728,0.00002259902],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9762977,0.0005824157,0.007896375,0.0001884726,0.00007395276,0.00002060737,0.0002960343,0.0001126473,0.01453184],"genre_scores_gemma":[0.9932326,0.0002241041,0.003649327,0.00008385388,0.00001306059,0.00001580956,0.0002080425,0.0000187335,0.002554538],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002907986,"threshold_uncertainty_score":0.009728193,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006045204565889011,"score_gpt":0.1975353001928666,"score_spread":0.1914900956269776,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}