{"id":"W3043192494","doi":"10.1139/v05-190","title":"Thermodynamics of organic mixtures containing amines. IV. Systems with aniline","year":2005,"lang":"en","type":"article","venue":"Canadian Journal of Chemistry","topic":"Thermodynamic properties of mixtures","field":"Chemical Engineering","cited_by":49,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"European Social Fund; Consejería de Educación, Junta de Castilla y León","keywords":"UNIFAC; Chemistry; Thermodynamics; Aniline; Ternary operation; Molar volume; Enthalpy; Alkane; Physical chemistry; Organic chemistry; Activity coefficient; Hydrocarbon","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":true,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001408789,0.0002025347,0.0003871305,0.0000640142,0.00003861824,0.00002721693,0.0004814126,0.0001587815,0.0001969987],"category_scores_gemma":[0.0001661205,0.0001602123,0.00008394654,0.0001148069,0.000113058,0.0001091515,0.00001447694,0.0004164824,0.000001682322],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003521125,"about_ca_system_score_gemma":0.0005540166,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004676897,"about_ca_topic_score_gemma":0.001266321,"domain_scores_codex":[0.9988272,0.00001162084,0.0004920971,0.000125311,0.000215413,0.000328365],"domain_scores_gemma":[0.9986502,0.00005158292,0.0003361479,0.0002531087,0.0002811841,0.0004277808],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00008157721,0.0000142157,0.0004247978,0.0001778784,0.0001670969,0.00008732617,0.0003973055,0.0142148,0.9835117,0.00003082236,0.0001541337,0.0007383003],"study_design_scores_gemma":[0.003498861,0.0002644752,0.000438256,0.001819633,0.0002166831,0.002962532,0.001993516,0.06726983,0.9150326,0.00005826477,0.005377422,0.001067891],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9910506,0.003974934,0.001370345,0.000191362,0.0000944866,0.00005458459,0.00002561321,0.00001795841,0.003220134],"genre_scores_gemma":[0.9987134,0.00001164888,0.0002983202,0.00003934836,0.0004100192,0.000001238976,0.000007793812,0.00005286095,0.0004653817],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.06847911,"threshold_uncertainty_score":0.6533266,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004768307993900488,"score_gpt":0.1731376294730714,"score_spread":0.1683693214791709,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}