{"id":"W3044179993","doi":"10.1039/d0ob01368d","title":"Discovery and properties of a new indigoid structure type based on dimeric <i>cis</i>-indigos","year":2020,"lang":"en","type":"article","venue":"Organic & Biomolecular Chemistry","topic":"Bioactive Compounds and Antitumor Agents","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":3,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"Natural Sciences and Engineering Research Council of Canada; University of Victoria","keywords":"Indigo; Chemistry; Indole test; Sodium hydride; Hydride; Stereochemistry; Redox; Crystallography; Photochemistry; Medicinal chemistry; Organic chemistry; Metal","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00007206621,0.000181443,0.0001199012,0.0001339511,0.0001138828,0.0002555745,0.0002853615,0.0002106068,0.001011658],"category_scores_gemma":[0.0001237694,0.0001262295,0.0001248025,0.0001022749,0.0002153938,0.0001735549,0.0001292995,0.0003801939,0.0002569925],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001782545,"about_ca_system_score_gemma":0.00009035687,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001951588,"about_ca_topic_score_gemma":0.0002340099,"domain_scores_codex":[0.9999624,0.000006617026,0.000001787419,0.00001177845,0.000008598525,0.000008797901],"domain_scores_gemma":[0.9999398,0.000007541489,0.00001485026,0.00001069113,0.000009032284,0.00001803727],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005437058,0.00001119712,0.0001190183,0.00002122533,0.000002637745,0.00004190176,0.00001192617,0.00007356226,0.9983063,0.000346112,0.00002495996,0.0009867992],"study_design_scores_gemma":[0.00000657694,0.0002170384,0.000569985,0.000002043276,0.00000668461,0.0002074025,0.00001319263,0.0003041302,0.9968875,0.00007966562,0.001702283,0.000003508959],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9885759,0.001254956,0.005821247,0.00009639088,0.00002715057,0.00002932788,0.0002141076,0.000089234,0.003891776],"genre_scores_gemma":[0.9941369,0.0003528572,0.003677254,0.00003750983,0.000006412067,0.000009891315,0.0002429403,0.0000146935,0.001521546],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001011658,"threshold_uncertainty_score":0.003384352,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.05923818239282216,"score_gpt":0.3229394996309035,"score_spread":0.2637013172380814,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}