{"id":"W3044678405","doi":"10.1002/chem.202002030","title":"Hierarchical Synthesis, Structure, and Photophysical Properties of Gallium‐ and Ruthenium‐Porphyrins with Axially Bonded Azo Ligands","year":2020,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Porphyrin and Phthalocyanine Chemistry","field":"Materials Science","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"University Postgraduate Programme; Natural Sciences and Engineering Research Council of Canada; Deutsche Forschungsgemeinschaft; Canada Foundation for Innovation","keywords":"Porphyrin; Chemistry; Ruthenium; Photochemistry; Ligand (biochemistry); Proton NMR; Intramolecular force; Isomerization; Crystallography; Stereochemistry; Catalysis; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008158223,0.0002501224,0.0001540637,0.000201379,0.0001107022,0.0002980454,0.0001811742,0.0001674027,0.000472442],"category_scores_gemma":[0.0001454406,0.000143415,0.0001160434,0.0001833606,0.0001794048,0.0001602869,0.000181302,0.0003061786,0.000237412],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004810491,"about_ca_system_score_gemma":0.0001971506,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006246262,"about_ca_topic_score_gemma":0.0008696421,"domain_scores_codex":[0.9999149,0.0000101548,0.000006484018,0.00002175349,0.00002178979,0.00002499562],"domain_scores_gemma":[0.9998953,0.00001308484,0.00003131504,0.00001487993,0.00001263046,0.00003270403],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001926556,0.000007164242,0.00003851042,0.00001629086,0.000002204072,0.00001263694,0.000006499831,0.0002202767,0.9988084,0.00007103004,0.00001098533,0.0007866611],"study_design_scores_gemma":[0.000007027876,0.00007716423,0.00087127,0.000001968532,0.000009248892,0.00003198761,0.000004860145,0.001266588,0.9970969,0.00003075481,0.0005985959,0.000003640149],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9940009,0.0005932769,0.003639362,0.00003748721,0.000007706204,0.00002421086,0.0001590757,0.0001258053,0.001412267],"genre_scores_gemma":[0.9954221,0.0002102932,0.003386619,0.00001418962,0.000003184098,0.00001626928,0.000113782,0.00001799909,0.0008154759],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0006246262,"threshold_uncertainty_score":0.003490329,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01519438985064793,"score_gpt":0.1838417777037221,"score_spread":0.1686473878530742,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}