{"id":"W3045978561","doi":"10.1016/j.isci.2020.101419","title":"Light-Driven Metal-Free Direct Deoxygenation of Alcohols under Mild Conditions","year":2020,"lang":"en","type":"article","venue":"iScience","topic":"Chemical Synthesis and Reactions","field":"Chemistry","cited_by":33,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University; Centre in Green Chemistry and Catalysis","funders":"Fonds Québécois de la Recherche sur la Nature et les Technologies; Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; Canada Foundation for Innovation; Lanzhou University","keywords":"Deoxygenation; Chemistry; Catalysis; Functional group; Bond cleavage; Dissociation (chemistry); Combinatorial chemistry; Molecule; Organic chemistry; Metal; Polymer","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00003966731,0.000070382,0.0001172728,0.00001806768,0.00009330926,0.00001688828,0.0003018052,0.00005008536,0.0008191465],"category_scores_gemma":[0.0002255327,0.00005750495,0.00008393006,0.0002372461,0.00009108992,0.0001132701,0.00007506389,0.00007547597,0.00003800945],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00002531423,"about_ca_system_score_gemma":0.00003098507,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002224893,"about_ca_topic_score_gemma":0.000007414711,"domain_scores_codex":[0.9992831,0.000006408882,0.0001546057,0.0002083994,0.0002242436,0.0001231859],"domain_scores_gemma":[0.9994696,0.00009283883,0.00007778706,0.0002143369,0.00004584741,0.00009953559],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000001454584,0.00004008258,0.00009403349,0.00001294844,0.00001368677,5.112106e-7,0.0001125507,0.00006912552,0.9970127,0.0006822183,0.001760626,0.0002001042],"study_design_scores_gemma":[0.0001087075,0.000005515479,0.001226888,0.00001903567,0.00002826583,0.000001640964,0.00008202309,0.0005068763,0.9894668,0.0005143094,0.007955898,0.00008404929],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.822978,0.0002761729,0.0003744827,0.01171602,0.00008002103,0.00006933026,0.0001095737,0.0001132545,0.1642831],"genre_scores_gemma":[0.9991005,0.00001614683,0.0002985622,0.0001676863,0.00006279251,0.000009230156,0.000006596712,0.000005734439,0.0003327465],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1761225,"threshold_uncertainty_score":0.8969079,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03780201296254879,"score_gpt":0.2715495077883939,"score_spread":0.2337474948258451,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}