{"id":"W3046215792","doi":"10.48336/8zx2-4h07","title":"Polyarene-based π-conjugated systems: synthesis, characterization, and mechanistic studies","year":2020,"lang":"en","type":"dissertation","venue":"Memorial University Research Repository (Memorial University)","topic":"Chemical Synthesis and Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"Memorial University of Newfoundland","funders":"","keywords":"Delocalized electron; Reactivity (psychology); Intramolecular force; Density functional theory; Chemistry; Microporous material; Cycloaddition; Conjugated system; Crystallinity; Alkyne; Photochemistry; Coupling reaction; Computational chemistry; Polymer chemistry; Polymer; Organic chemistry; Crystallography; Catalysis","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts"],"consensus_categories":[],"category_scores_codex":[0.0003578649,0.0006078684,0.001065737,0.0008044253,0.001990368,0.0002826421,0.001001843,0.001025164,0.0001683717],"category_scores_gemma":[0.000978413,0.0007039458,0.0003184021,0.001121279,0.000442356,0.0003730578,0.0003084485,0.001327818,0.00003912899],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.001579648,"about_ca_system_score_gemma":0.001228648,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009742304,"about_ca_topic_score_gemma":0.0001234192,"domain_scores_codex":[0.9957676,0.0005864847,0.0004410306,0.001318856,0.001169909,0.0007161221],"domain_scores_gemma":[0.9957247,0.001281657,0.000471815,0.0006224305,0.001269071,0.0006303509],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.004750813,0.0002381743,0.0000490767,0.002027781,0.001054867,0.001798483,0.0005276429,0.000009840635,0.9842713,0.003024391,0.0016639,0.0005836849],"study_design_scores_gemma":[0.002694801,0.0001667884,0.00005449239,0.001681531,0.001533585,0.00002414975,0.02087007,0.0005622003,0.5365593,0.00003920563,0.4344243,0.001389586],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8687224,0.0008439891,0.0001609825,0.000639577,0.01805218,0.001618438,0.00109916,0.001127767,0.1077354],"genre_scores_gemma":[0.8404133,0.001746429,0.00006755136,0.000008725932,0.008643953,0.000007047609,0.002081163,0.0001749616,0.1468568],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.447712,"threshold_uncertainty_score":0.9995412,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03209232425766124,"score_gpt":0.2604811285784045,"score_spread":0.2283888043207433,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}