{"id":"W3049291205","doi":"10.1002/jrs.5964","title":"The systematical detection and structure characterization of vanadium‐oxygen species in low concentration solutions by surface‐enhanced Raman spectroscopy experiments and density functional theory calculations","year":2020,"lang":"en","type":"article","venue":"Journal of Raman Spectroscopy","topic":"Electrochemical Analysis and Applications","field":"Chemistry","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"Ministry of Education and Child Care","funders":"Specialized Research Fund for the Doctoral Program of Higher Education of China; National Natural Science Foundation of China","keywords":"Vanadium; Raman spectroscopy; Density functional theory; Oxygen; Surface-enhanced Raman spectroscopy; Chemistry; Characterization (materials science); Spectroscopy; Nanoparticle; Electrochemistry; Inorganic chemistry; Electrode; Analytical Chemistry (journal); Materials science; Raman scattering; Nanotechnology; Physical chemistry; Computational chemistry; Environmental chemistry; Organic chemistry; Optics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005093587,0.0004656929,0.0002515046,0.0004220582,0.0003539847,0.0002331692,0.0006240669,0.0004399392,0.0008918314],"category_scores_gemma":[0.0006759843,0.0002604803,0.0004606496,0.0002144698,0.0003043967,0.000369901,0.0003152313,0.0005834147,0.0001468711],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003105033,"about_ca_system_score_gemma":0.000282029,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001219372,"about_ca_topic_score_gemma":0.001426977,"domain_scores_codex":[0.9998097,0.00003938488,0.00000822113,0.00002948039,0.00008961943,0.00002366921],"domain_scores_gemma":[0.9998248,0.00006612939,0.00001769786,0.00002742261,0.00005951148,0.000004580773],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007998192,0.0001070428,0.001257134,0.0004156828,0.00004484799,0.0001020664,0.0001192463,0.01993757,0.954672,0.007800883,0.000430745,0.01503288],"study_design_scores_gemma":[0.00002671818,0.0001900034,0.002245021,0.0000241283,0.00003029485,0.00006469937,0.00008512328,0.3102391,0.6836277,0.002085166,0.001347947,0.00003403482],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.904076,0.001253715,0.08859882,0.0002793581,0.0000859748,0.00008804361,0.0003224246,0.0002563998,0.005039242],"genre_scores_gemma":[0.9691479,0.0004566183,0.02972692,0.00003091514,0.000006771522,0.00006475456,0.0001600246,0.00002208925,0.0003839586],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001219372,"threshold_uncertainty_score":0.00298351,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008023510984397865,"score_gpt":0.2201268988455168,"score_spread":0.2121033878611189,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}