{"id":"W3049697770","doi":"10.1002/marc.202000375","title":"Reversible Redox Crosslinking of Thiopropylsilicones","year":2020,"lang":"en","type":"article","venue":"Macromolecular Rapid Communications","topic":"Synthesis and properties of polymers","field":"Materials Science","cited_by":12,"is_retracted":false,"has_abstract":true,"ca_institutions":"McMaster University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Elastomer; Silicone; Thermosetting polymer; Materials science; Redox; Polymer chemistry; Disulfide bond; Polymer; Hydrosilylation; Wetting; Chemical engineering; Chemistry; Organic chemistry; Composite material; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002708248,0.000108661,0.0002030553,0.00003335401,0.0002602985,0.00005685198,0.001441091,0.0000523323,0.000785245],"category_scores_gemma":[0.000171016,0.0001022673,0.0001074829,0.0002084903,0.0003244805,0.0001099994,0.000540514,0.0001085961,0.0001798828],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001169334,"about_ca_system_score_gemma":0.00005083904,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001058389,"about_ca_topic_score_gemma":0.000004421718,"domain_scores_codex":[0.9989316,0.0001979906,0.000312455,0.0001972489,0.0001809956,0.0001796962],"domain_scores_gemma":[0.9982949,0.00008478723,0.000151663,0.001311329,0.00008806915,0.00006928534],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001625591,0.0000369005,0.00006128797,0.00002706912,0.00001437154,0.000001355629,0.001095345,0.000009160249,0.9911854,0.001754182,0.000307238,0.005491448],"study_design_scores_gemma":[0.0001729034,0.00006068299,0.0000809881,0.00003824778,0.00002579625,0.000003683271,0.000337967,0.0004646117,0.963048,0.0001677175,0.03546038,0.000139031],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8724973,0.03444281,0.003356191,0.0380569,0.0002626869,0.0006701856,0.0001006814,0.0003875984,0.0502257],"genre_scores_gemma":[0.9887823,0.0003075119,0.009916744,0.0008680713,0.00001770943,0.00001790348,0.000009894339,0.0000187775,0.00006108384],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.116285,"threshold_uncertainty_score":0.8597882,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04200632570538029,"score_gpt":0.2604517870701727,"score_spread":0.2184454613647925,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}