{"id":"W3073976798","doi":"10.1038/s41428-020-00395-6","title":"Iron-catalyzed reactions of CO2 and epoxides to yield cyclic and polycarbonates","year":2020,"lang":"en","type":"article","venue":"Polymer Journal","topic":"Carbon dioxide utilization in catalysis","field":"Chemical Engineering","cited_by":38,"is_retracted":false,"has_abstract":false,"ca_institutions":"Memorial University of Newfoundland","funders":"","keywords":"Catalysis; Chemistry; Epoxide; Lewis acids and bases; Cobalt; Cyclohexene oxide; Nucleophile; Polymerization; Polymer chemistry; Ring-opening polymerization; Organic chemistry; Polymer","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001816693,0.0003085504,0.000126713,0.0003114921,0.0001944372,0.0001949157,0.0002459114,0.0003090694,0.001611005],"category_scores_gemma":[0.0002912201,0.00008930309,0.0001722236,0.0001968523,0.0002643228,0.0003128406,0.0002078066,0.0004544054,0.0002749782],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0005049613,"about_ca_system_score_gemma":0.0003515189,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0015071,"about_ca_topic_score_gemma":0.004089076,"domain_scores_codex":[0.9998926,0.000009361769,0.000004910011,0.00001636173,0.00002989867,0.0000468746],"domain_scores_gemma":[0.9999058,0.00002590215,0.00001584481,0.00001140291,0.0000188387,0.00002213714],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004351143,0.0001408151,0.0005018777,0.0002643538,0.00002739706,0.0006416599,0.0001317949,0.001000328,0.9715596,0.004981735,0.001006466,0.01930878],"study_design_scores_gemma":[0.00002145022,0.0001679804,0.000972526,0.000008304097,0.000008707318,0.0001719211,0.00001184829,0.001078106,0.9917123,0.000179037,0.005658333,0.000009439921],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9681696,0.002262385,0.007668809,0.0002886847,0.0001771478,0.00007817338,0.0001936768,0.0001827268,0.02097866],"genre_scores_gemma":[0.993922,0.0005100482,0.001478045,0.00003740421,0.00001355389,0.00001037857,0.00011306,0.00001759168,0.00389795],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001611005,"threshold_uncertainty_score":0.005389333,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01870476267327609,"score_gpt":0.2359197405796448,"score_spread":0.2172149779063688,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}