{"id":"W3080347583","doi":"10.1021/acs.joc.0c01115","title":"Unusual Acetonitrile Adduct Formed via Photolysis of 4′-Chloro-2-Hydroxybiphenyl in Aqueous Solution","year":2020,"lang":"en","type":"article","venue":"The Journal of Organic Chemistry","topic":"Photochemistry and Electron Transfer Studies","field":"Chemistry","cited_by":9,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Victoria","funders":"University of Hong Kong; Research Grants Council, University Grants Committee; National Natural Science Foundation of China","keywords":"Chemistry; Acetonitrile; Adduct; Aqueous solution; Photodissociation; Photochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0003113638,0.0002636096,0.0005702209,0.00002062845,0.00009040657,0.00001134922,0.0006662896,0.0001720689,0.002133694],"category_scores_gemma":[0.0002317286,0.0002091098,0.0002202991,0.0003866912,0.0001589294,0.0001092455,0.00009140482,0.0007863267,0.000004619774],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001749162,"about_ca_system_score_gemma":0.0002310981,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000172514,"about_ca_topic_score_gemma":0.000007479741,"domain_scores_codex":[0.9981562,0.00002406013,0.0008385183,0.0001797652,0.000423123,0.0003783564],"domain_scores_gemma":[0.9987999,0.0001514309,0.000468953,0.0002790346,0.000148943,0.0001517994],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0005819886,0.0001266141,0.0002937787,0.000416842,0.0002257523,0.00002507911,0.001401306,0.00001973532,0.9958034,2.981164e-7,0.0002978616,0.0008074053],"study_design_scores_gemma":[0.001350839,0.00005719924,0.0000304296,0.0001013099,0.000204321,0.0003320083,0.000864247,0.0002109806,0.9962008,0.0001505767,0.0003007771,0.0001965233],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9938515,0.002215174,0.0004406291,0.0008002113,0.00002922973,0.00005327757,0.00001696345,0.00002319871,0.002569813],"genre_scores_gemma":[0.998894,0.0005377837,0.00004357534,0.00007196675,0.0003074159,0.000003325327,0.000007507002,0.00002939348,0.0001050686],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.005042461,"threshold_uncertainty_score":0.9987785,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01110009905734988,"score_gpt":0.2159783805812322,"score_spread":0.2048782815238823,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}