{"id":"W3080428912","doi":"10.1002/ange.202009867","title":"A Pure‐Red Doublet Emission with 90 % Quantum Yield: Stable, Colorless, Iodinated Triphenylmethane Solid","year":2020,"lang":"en","type":"article","venue":"Angewandte Chemie","topic":"Luminescence and Fluorescent Materials","field":"Materials Science","cited_by":10,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Quantum yield; Triphenylmethane; Photoluminescence; Photochemistry; Excited state; Luminescence; Chemistry; Yield (engineering); Materials science; Physical chemistry; Atomic physics; Fluorescence; Optoelectronics; Optics; Organic chemistry; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0003205094,0.0003672772,0.0006002673,0.00005016566,0.0001730457,0.0002233259,0.0004966346,0.0001970288,0.002206768],"category_scores_gemma":[0.0001865026,0.0002731859,0.00007540077,0.0003663111,0.0001530693,0.000401415,0.0001638092,0.0001312658,0.0002460036],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006043692,"about_ca_system_score_gemma":0.0001541473,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00007233093,"about_ca_topic_score_gemma":0.000006518337,"domain_scores_codex":[0.9976899,0.0000521057,0.0004522367,0.0006643321,0.0004775407,0.0006638555],"domain_scores_gemma":[0.9987488,0.00006356725,0.0002395122,0.0003924235,0.0001673102,0.0003883314],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.001404232,0.00009442583,0.0002280456,0.0002046763,0.00001882089,0.0001206596,0.0006761725,0.000004090573,0.9702828,0.00001887522,0.02691778,0.00002940769],"study_design_scores_gemma":[0.001598385,0.0002268656,0.00004960911,0.0001608599,0.0000562598,0.00002004706,0.0002513119,0.00004424324,0.9904675,0.00004597166,0.006660495,0.0004184204],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9940376,0.00016449,0.0001026328,0.003140866,0.0003511974,0.0004819948,0.0001150358,0.0003489989,0.001257208],"genre_scores_gemma":[0.9969268,0.00008019196,0.0005763967,0.001170854,0.0004078053,0.00005584879,0.0001250313,0.00005083999,0.0006062001],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.02025728,"threshold_uncertainty_score":0.999972,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03350594961898592,"score_gpt":0.2510332928167988,"score_spread":0.2175273431978128,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}