{"id":"W3080926199","doi":"10.1039/d0cs00229a","title":"Titanium catalysis for the synthesis of fine chemicals – development and trends","year":2020,"lang":"en","type":"review","venue":"Chemical Society Reviews","topic":"Synthesis and Catalytic Reactions","field":"Chemistry","cited_by":194,"is_retracted":false,"has_abstract":true,"ca_institutions":"Vancouver Biotech (Canada); University of British Columbia","funders":"Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; Alexander von Humboldt-Stiftung","keywords":"Titan (rocket family); Titanium; Catalysis; Transition metal; Chemistry; Nanotechnology; Astrobiology; Materials science; Organic chemistry; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0004145137,0.0005368938,0.003024332,0.00001448375,0.0001104255,0.00003291338,0.0005933765,0.0004517717,0.0004466169],"category_scores_gemma":[0.0008264208,0.0003142622,0.002703207,0.0003549055,0.0001829314,0.00003001481,0.0001931595,0.0003507061,0.00002714208],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001711468,"about_ca_system_score_gemma":0.0001139388,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000002873637,"about_ca_topic_score_gemma":3.672282e-7,"domain_scores_codex":[0.9975283,0.00001819789,0.001338982,0.000604363,0.0002209585,0.000289252],"domain_scores_gemma":[0.9964725,0.001864736,0.0007997354,0.0006630702,0.00004696433,0.000153014],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"not_applicable","study_design_scores_codex":[0.000001638584,0.00004206615,1.187455e-7,0.0262152,0.0006200665,1.44989e-7,0.00005477027,2.535194e-9,0.001265432,0.000008580087,0.01490258,0.9568894],"study_design_scores_gemma":[0.00005934344,0.000001530132,6.295824e-8,0.004704297,0.003762189,0.00001035684,0.00002894664,0.000005133123,0.02949347,0.000002658698,0.9616148,0.000317214],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"review","genre_gemma":"review","genre_scores_codex":[0.000001929529,0.9981109,0.00004920294,0.0001650528,0.00002732341,0.0003021636,0.0001298917,0.00002909763,0.00118441],"genre_scores_gemma":[0.000003140374,0.9938242,0.003137399,0.00003226604,0.0002990145,0.001606936,0.0002833031,0.00006264745,0.0007511303],"genre_candidate":"review","genre_consensus":"review","teacher_disagreement_score":0.9565722,"threshold_uncertainty_score":0.9999309,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.07298396143826413,"score_gpt":0.3209360937812149,"score_spread":0.2479521323429508,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}