{"id":"W3081848707","doi":"10.1002/ejoc.202001019","title":"Metal‐Free Alkenylation of Salicylaldehydes with Boronic Acids: Synthesis of Skipped Dienes and 2<i>H</i>‐Chromenes","year":2020,"lang":"en","type":"article","venue":"European Journal of Organic Chemistry","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":11,"is_retracted":false,"has_abstract":true,"ca_institutions":"Ontario Tech University; University of Calgary","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Chemistry; Organic chemistry; Metal; Salicylaldehyde; Boronic acid; Ether; Polymer chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0005426042,0.0002092096,0.0004813655,0.00003555574,0.00004359138,0.00001995124,0.0003941259,0.00004585242,0.002900629],"category_scores_gemma":[0.00154412,0.0001799662,0.0001175054,0.0002683508,0.0001798664,0.0001438059,0.0001491844,0.0001901429,0.000002140001],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00004514751,"about_ca_system_score_gemma":0.0001553144,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000001129268,"about_ca_topic_score_gemma":4.70989e-7,"domain_scores_codex":[0.9982976,0.0000795039,0.000821968,0.0002195623,0.0004382275,0.0001430968],"domain_scores_gemma":[0.9977988,0.0002683331,0.001115825,0.0003358191,0.0003116172,0.0001695755],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002107681,0.00006280376,0.001822049,0.0007616082,0.0002910049,0.0000293411,0.0003489348,0.00004155117,0.9938651,0.000008925093,0.0001674244,0.002390518],"study_design_scores_gemma":[0.001118514,0.00007560477,0.001145372,0.0002542554,0.000317794,0.0002701381,0.000512446,0.00004363399,0.9936306,0.00002740629,0.002428635,0.0001755607],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9878564,0.00152377,0.00250875,0.0006111255,0.00003693883,0.00003709323,0.00004967532,0.00003150378,0.007344777],"genre_scores_gemma":[0.9953278,0.0002090685,0.003849542,0.00002977743,0.00027402,5.431801e-7,0.00001030905,0.0000622783,0.0002366149],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.007471481,"threshold_uncertainty_score":0.9980109,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01480916744824542,"score_gpt":0.2183089639794302,"score_spread":0.2034997965311848,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}