{"id":"W3088504638","doi":"10.1002/chem.202003828","title":"Gram‐Scale Synthesis of the 1,1,<i>n</i>,<i>n</i>‐Tetramethyl[<i>n</i>](2,11)teropyrenophanes","year":2020,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"DNA and Nucleic Acid Chemistry","field":"Biochemistry, Genetics and Molecular Biology","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"Wilfrid Laurier University; Memorial University of Newfoundland","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Gram; Halogenation; Alkylation; Chemistry; Scale (ratio); Combinatorial chemistry; Stereochemistry; Organic chemistry; Catalysis; Bacteria; Physics; Biology","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001597592,0.0004762573,0.0003206747,0.0002159863,0.0002308247,0.0001883395,0.0003069078,0.0001846806,0.003955278],"category_scores_gemma":[0.0001994479,0.0001642974,0.0002303231,0.0002853435,0.0001667208,0.0003320046,0.0003516999,0.0005125771,0.001289509],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002723591,"about_ca_system_score_gemma":0.0004826035,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004165362,"about_ca_topic_score_gemma":0.001133885,"domain_scores_codex":[0.9998902,0.00001439275,0.000009141299,0.00002351526,0.00002968149,0.00003303661],"domain_scores_gemma":[0.9999478,0.000006737822,0.00001018023,0.0000124309,0.000009230605,0.00001367282],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00009326082,0.00004199492,0.0001344213,0.0002944404,0.000009951389,0.0003806575,0.0001014415,0.0007380755,0.9868305,0.001897013,0.0004235791,0.009054589],"study_design_scores_gemma":[0.00003483243,0.0006078884,0.0009124783,0.00002736376,0.00001893671,0.0003776558,0.00004943294,0.0006541291,0.9803997,0.0003521374,0.01654338,0.00002197193],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9268752,0.002628829,0.03747794,0.0002894506,0.0002264722,0.0006370582,0.003305614,0.000566203,0.02799318],"genre_scores_gemma":[0.9471118,0.004625111,0.03746711,0.00007056792,0.0000270712,0.0002831547,0.001646981,0.0001074322,0.008660802],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003955278,"threshold_uncertainty_score":0.01323169,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.008051101729064295,"score_gpt":0.1911935381657126,"score_spread":0.1831424364366483,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}