{"id":"W3091337548","doi":"10.1039/d0cc05895e","title":"Boronic acid-mediated ring-opening and Ni-catalyzed arylation of 1-arylcyclopropyl tosylates","year":2020,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Catalytic C–H Functionalization Methods","field":"Chemistry","cited_by":13,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto; Toronto Public Health","funders":"Natural Sciences and Engineering Research Council of Canada; Ontario Ministry of Research, Innovation and Science; Canada Research Chairs; Kennarshore; University of Toronto; Canada Foundation for Innovation","keywords":"Regioselectivity; Ring (chemistry); Catalysis; Chemistry; Boronic acid; Combinatorial chemistry; Molecule; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001886344,0.0006808148,0.0003434756,0.000291641,0.0003713479,0.0001935582,0.0005003402,0.0003519075,0.002225063],"category_scores_gemma":[0.0002261455,0.0001657963,0.0002392049,0.0002944242,0.0002403647,0.00038929,0.0003810537,0.0006726435,0.0008385805],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004360091,"about_ca_system_score_gemma":0.0006452193,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001198183,"about_ca_topic_score_gemma":0.003604175,"domain_scores_codex":[0.9997706,0.00003087621,0.0000207055,0.00003731436,0.0000545841,0.00008592896],"domain_scores_gemma":[0.9999307,0.000009920076,0.00001912405,0.00001096566,0.00001071041,0.00001862025],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001730748,0.00007572465,0.000129356,0.0004582499,0.00001845858,0.0004700153,0.0001411007,0.0008476464,0.9819145,0.002135087,0.0006678054,0.01296887],"study_design_scores_gemma":[0.00001888657,0.0002144425,0.0003279182,0.00001214771,0.00001019805,0.0002161565,0.00002248173,0.0005786808,0.9895802,0.0001452135,0.00885932,0.0000144082],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8984263,0.009776004,0.04769226,0.0006855112,0.0003435921,0.0005303589,0.001673158,0.0007999166,0.04007289],"genre_scores_gemma":[0.9698265,0.00516053,0.01605412,0.0001032961,0.00005178769,0.0001778321,0.0007969821,0.00006316234,0.007765858],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002225063,"threshold_uncertainty_score":0.007443607,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04563523211847878,"score_gpt":0.296796116622021,"score_spread":0.2511608845035422,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}