{"id":"W3091804010","doi":"10.1002/anie.202009867","title":"A Pure‐Red Doublet Emission with 90 % Quantum Yield: Stable, Colorless, Iodinated Triphenylmethane Solid","year":2020,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Luminescence and Fluorescent Materials","field":"Materials Science","cited_by":95,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Triphenylmethane; Quantum yield; Photoluminescence; Photochemistry; Excited state; Chemistry; Luminescence; Yield (engineering); Physical chemistry; Materials science; Fluorescence; Atomic physics; Optics; Optoelectronics; Organic chemistry; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00008117606,0.0003026729,0.0001467881,0.0001772496,0.0001843755,0.0002387877,0.0002554162,0.0001993004,0.002462902],"category_scores_gemma":[0.00008759776,0.0001316445,0.0001138166,0.0001584311,0.000170612,0.0001350329,0.000182534,0.0002821258,0.001041071],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002331503,"about_ca_system_score_gemma":0.0001854951,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003962232,"about_ca_topic_score_gemma":0.0005173822,"domain_scores_codex":[0.9999244,0.000006555446,0.000002987008,0.00001965617,0.00003160771,0.00001482409],"domain_scores_gemma":[0.9999301,0.00001089329,0.00002066889,0.000009685772,0.00001082263,0.00001784295],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0000214044,0.000009411259,0.00007410058,0.00002009856,0.00000182149,0.00005185941,0.00001620322,0.00004417146,0.9984323,0.0001015608,0.000141008,0.001086048],"study_design_scores_gemma":[0.000004100759,0.00005761289,0.0005454448,0.000001761978,0.000002112646,0.00009880785,0.000007234685,0.0002778759,0.9977304,0.00002255601,0.001249428,0.000002659158],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9777231,0.0005109874,0.01052412,0.0001379034,0.00003398952,0.00003779219,0.001078392,0.0005530811,0.009400572],"genre_scores_gemma":[0.9892426,0.000186346,0.004367346,0.00002157507,0.000004440979,0.00002441516,0.0005280845,0.00009989846,0.005525377],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002462902,"threshold_uncertainty_score":0.00823921,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02870107655636995,"score_gpt":0.2610644002601524,"score_spread":0.2323633237037825,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}