{"id":"W3091898437","doi":"10.1039/d0sc04500d","title":"Bis[pyrrolyl Ru( <scp>ii</scp> )] triads: a new class of photosensitizers for metal–organic photodynamic therapy","year":2020,"lang":"en","type":"article","venue":"Chemical Science","topic":"Porphyrin and Phthalocyanine Chemistry","field":"Materials Science","cited_by":31,"is_retracted":false,"has_abstract":true,"ca_institutions":"Acadia University; Dalhousie University","funders":"National Cancer Institute; Natural Sciences and Engineering Research Council of Canada; National Institutes of Health","keywords":"Photodynamic therapy; Chemistry; Metal; Ruthenium; Combinatorial chemistry; Stereochemistry; Medicinal chemistry; Organic chemistry; Catalysis","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0005288655,0.0002776512,0.0004726771,0.00004578174,0.0001721329,0.00007814879,0.001238109,0.0001339796,0.0002035347],"category_scores_gemma":[0.001353386,0.0002354163,0.000194904,0.0009772325,0.0008194405,0.0002503312,0.0002749096,0.0001673221,0.00003788203],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008335587,"about_ca_system_score_gemma":0.000657699,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00002310032,"about_ca_topic_score_gemma":6.534978e-7,"domain_scores_codex":[0.9973981,0.00001803848,0.0004532212,0.0008192462,0.0006282288,0.000683158],"domain_scores_gemma":[0.9982631,0.0002878929,0.0002527455,0.0004207819,0.000149301,0.0006262069],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005262285,0.00006110103,0.000008767895,0.00004023675,0.000007288376,0.000002696835,0.0004310464,0.000003313295,0.9973157,0.00006678253,0.001895592,0.0001148403],"study_design_scores_gemma":[0.001252346,0.0001419726,0.0000139705,0.00002097607,0.00001784773,0.00001550668,0.0001222397,0.0006957134,0.9936568,0.000313772,0.003613615,0.0001352477],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9963,0.0002080659,0.0002934352,0.0004978234,0.0002118342,0.0003787192,0.00005408063,0.000124946,0.001931081],"genre_scores_gemma":[0.9968315,0.00002384981,0.001705647,0.0008681951,0.0002076555,0.0000208454,0.00001074221,0.00002634472,0.0003051943],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003658919,"threshold_uncertainty_score":0.96,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02454269436843345,"score_gpt":0.2568184183469486,"score_spread":0.2322757239785151,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}