{"id":"W3092352189","doi":"10.1002/anie.202011372","title":"Reversible Silylium Transfer between P‐H and Si‐H Donors","year":2020,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Organoboron and organosilicon chemistry","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta; University of Victoria","funders":"Natural Sciences and Engineering Research Council of Canada; Max-Planck-Gesellschaft","keywords":"Silane; Electrophile; Adduct; Chemistry; Silanes; Phosphine; Lewis acids and bases; Hydrosilylation; Catalysis; Medicinal chemistry; Polymer chemistry; Ligand (biochemistry); Photochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0000876728,0.0002222404,0.0001163076,0.00009015805,0.000129564,0.00018804,0.0003111208,0.0001443826,0.003521519],"category_scores_gemma":[0.0001196558,0.0001215689,0.00008075881,0.0000698631,0.0001976943,0.0002941568,0.0003879454,0.0002756797,0.0004610197],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001839359,"about_ca_system_score_gemma":0.0001206147,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002013786,"about_ca_topic_score_gemma":0.0003291232,"domain_scores_codex":[0.9999421,0.000007920981,0.000002113498,0.00001215988,0.00001318922,0.00002242003],"domain_scores_gemma":[0.999958,0.00001362961,0.000008294722,0.000006936067,0.000003587608,0.00000943485],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001700115,0.00002996874,0.000204469,0.0001146875,0.0000100656,0.000193802,0.00008481087,0.0003142136,0.9913175,0.002189237,0.0002071123,0.00516402],"study_design_scores_gemma":[0.00001598535,0.0001114999,0.0002356981,0.000001963651,0.00000325023,0.00005958302,0.00001513718,0.0008997565,0.9969224,0.000144321,0.001587128,0.000003163414],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9910508,0.0002663738,0.00266843,0.00004651956,0.00002054955,0.00002052891,0.0000506522,0.0001212779,0.005754862],"genre_scores_gemma":[0.9975746,0.00008889295,0.0004643071,0.00001160101,0.000003510695,0.000006438242,0.00002825668,0.0000092852,0.001813024],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003521519,"threshold_uncertainty_score":0.01178068,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01835456808945486,"score_gpt":0.2354926480448915,"score_spread":0.2171380799554366,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}