{"id":"W3092643064","doi":"10.1002/chem.202004153","title":"Iminophosphorano‐Substituted Bispyridinylidenes: Redox Potentials and Substituent Constants from Tolman Electronic Parameters","year":2020,"lang":"en","type":"article","venue":"Chemistry - A European Journal","topic":"Chemical Reaction Mechanisms","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of New Brunswick","funders":"Natural Sciences and Engineering Research Council of Canada; New Brunswick Innovation Foundation; Canada Foundation for Innovation","keywords":"Substituent; Redox; Chemistry; Phosphine; Computational chemistry; Stereochemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002456628,0.0003454331,0.0001407129,0.0001959656,0.00006138345,0.0002735127,0.0002927688,0.000196053,0.0009195983],"category_scores_gemma":[0.0005639073,0.000143444,0.00009923341,0.0002004182,0.0001497381,0.0004554687,0.0001664609,0.0004238809,0.000181443],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002697779,"about_ca_system_score_gemma":0.00009639795,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003458,"about_ca_topic_score_gemma":0.0005326673,"domain_scores_codex":[0.9999318,0.0000174346,0.000003892416,0.00001968188,0.00002037666,0.000006722266],"domain_scores_gemma":[0.9998361,0.00008919011,0.00004325887,0.00001224951,0.00001254913,0.00000660721],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0004293728,0.00009056741,0.002884747,0.0004771898,0.00004403984,0.0001389357,0.0001139244,0.03369699,0.9110287,0.01134244,0.0004961282,0.03925691],"study_design_scores_gemma":[0.00001557554,0.0004418749,0.00243261,0.00002628313,0.00003188963,0.00009514422,0.00004513391,0.08579531,0.9051512,0.002542392,0.003389631,0.00003298284],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.95859,0.002497228,0.0339453,0.0001030833,0.00003645419,0.00001833105,0.000393833,0.0001953074,0.004220488],"genre_scores_gemma":[0.9908528,0.001141263,0.006958042,0.00001918607,0.000003939571,0.00001557088,0.0002516691,0.00001618186,0.000741455],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009195983,"threshold_uncertainty_score":0.003076375,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01930267682370937,"score_gpt":0.2069919987619728,"score_spread":0.1876893219382635,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}