{"id":"W3093610548","doi":"10.1021/acs.jpcb.0c05946","title":"Gibbsian Surface Thermodynamics","year":2020,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry B","topic":"nanoparticles nucleation surface interactions","field":"Earth and Planetary Sciences","cited_by":52,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"Natural Sciences and Engineering Research Council of Canada","keywords":"Thermodynamics; Gibbs–Helmholtz equation; Work (physics); Equation of state; Surface tension; Non-equilibrium thermodynamics; Thermodynamic equations; Statistical physics; Gibbs free energy; Equilibrium thermodynamics; Gibbs isotherm; Chemistry; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00009382136,0.00006043618,0.0001003622,0.000002414431,0.00005551641,0.00002130565,0.0002458817,0.00001511951,0.0009734511],"category_scores_gemma":[0.00005439511,0.00003619312,0.00007076251,0.0001157498,0.00006882532,0.0001337874,0.00000715397,0.0002243139,0.0001531525],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000003748892,"about_ca_system_score_gemma":0.00002568774,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001527222,"about_ca_topic_score_gemma":0.000002719711,"domain_scores_codex":[0.999476,0.00003608863,0.0001486582,0.0000454735,0.0001984107,0.0000953897],"domain_scores_gemma":[0.999417,0.0001920471,0.0001393867,0.00007684831,0.00005537977,0.0001193528],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"simulation_or_modeling","study_design_scores_codex":[0.0001623525,0.00003857721,0.003230082,0.000013354,0.00004684631,0.00000919862,0.00181296,0.1566714,0.834458,0.00001154438,0.0008534372,0.002692242],"study_design_scores_gemma":[0.0005948814,0.0003206198,0.025165,0.00002807295,0.0001288855,0.0001339593,0.002571837,0.6238906,0.3393433,0.001181333,0.006375364,0.0002661225],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9912503,0.00003457794,0.0001201632,0.004431961,0.00002827953,0.0000194947,0.000009733945,0.00000958598,0.004095883],"genre_scores_gemma":[0.9993987,0.000004987745,0.00007147715,0.0002176523,0.0002523023,1.085883e-8,0.000001348232,0.00000246693,0.00005106977],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4951147,"threshold_uncertainty_score":0.9999398,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01430685600693998,"score_gpt":0.2237594621186802,"score_spread":0.2094526061117402,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}