{"id":"W3093912291","doi":"10.1021/acs.chemrev.0c00346","title":"Selective Carbon–Carbon Bond Cleavage of Cyclopropanols","year":2020,"lang":"en","type":"review","venue":"Chemical Reviews","topic":"Fluorine in Organic Chemistry","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":303,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"University of Toronto; Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs","keywords":"Chemistry; Cleavage (geology); Bond cleavage; Carbon fibers; Reinforced carbon–carbon; Carbon–carbon bond; Bond; Organic chemistry; Composite number; Catalysis; Business; Composite material","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","research_integrity"],"consensus_categories":["research_integrity"],"category_scores_codex":[0.0006970401,0.0009989189,0.005062031,0.00007029193,0.00003793524,0.00001082003,0.001139009,0.001687418,0.0003053978],"category_scores_gemma":[0.002208694,0.0008392942,0.00117071,0.0008835484,0.0003581201,0.00002709954,0.0005037438,0.003785205,0.0002339033],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004350067,"about_ca_system_score_gemma":0.0005080185,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00000614553,"about_ca_topic_score_gemma":3.078708e-7,"domain_scores_codex":[0.9954379,0.0004367989,0.002168333,0.001021866,0.0002755625,0.00065955],"domain_scores_gemma":[0.9965031,0.0008164966,0.001341109,0.0007471317,0.00009690627,0.000495256],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"design_other","study_design_gemma":"not_applicable","study_design_scores_codex":[0.00003135978,0.0002033151,0.000009023675,0.06004385,0.0004830792,0.00005777601,0.00007147898,1.191236e-8,0.02762348,0.00003018777,0.03903512,0.8724113],"study_design_scores_gemma":[0.0002725608,0.00003333358,8.419873e-8,0.004073325,0.002016535,0.00007147484,0.000002972115,0.000003371313,0.168642,0.00004225117,0.8242822,0.0005598763],"study_design_candidate":"design_other","study_design_consensus":null,"genre_codex":"review","genre_gemma":"review","genre_scores_codex":[0.00005846522,0.9428213,3.216628e-7,0.00008162846,0.0005299198,0.001781468,0.00007460497,0.0001104729,0.05454186],"genre_scores_gemma":[0.0001069783,0.9972563,0.0001377704,0.0002287415,0.001145642,0.0003556834,0.0001232262,0.0001557371,0.0004898547],"genre_candidate":"review","genre_consensus":"review","teacher_disagreement_score":0.8718514,"threshold_uncertainty_score":0.9996086,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.1768103273683576,"score_gpt":0.4725042422940419,"score_spread":0.2956939149256843,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}