{"id":"W3094207965","doi":"10.1021/acs.jpcc.0c05521","title":"Naphthalenediimide Cations Inhibit 2D Perovskite Formation and Facilitate Subpicosecond Electron Transfer","year":2020,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry C","topic":"Perovskite Materials and Applications","field":"Engineering","cited_by":22,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Air Force Office of Scientific Research; Division of Electrical, Communications and Cyber Systems; Office of Naval Research; Natural Sciences and Engineering Research Council of Canada; U.S. Navy; University of Toronto; National Science Foundation","keywords":"Formamidinium; Perovskite (structure); Chemistry; Halide; Photoluminescence; Chemical physics; Ultrafast laser spectroscopy; Molecule; Photochemistry; Crystallography; Materials science; Inorganic chemistry; Spectroscopy; Optoelectronics; Organic chemistry; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006595073,0.00008820153,0.0001283914,0.000006563932,0.00005092885,0.0000248343,0.0001063959,0.00002442971,0.00002629029],"category_scores_gemma":[0.000009981956,0.00006371026,0.00004870393,0.0000685952,0.00003379515,0.0001603386,0.000009344029,0.000165278,0.000006611695],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001987587,"about_ca_system_score_gemma":0.000009619526,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":9.609323e-7,"about_ca_topic_score_gemma":3.389316e-7,"domain_scores_codex":[0.9995486,0.00001111763,0.000193715,0.00004513583,0.00009561014,0.0001058443],"domain_scores_gemma":[0.9997331,0.00004340218,0.00002967396,0.00006997316,0.00003861048,0.00008526428],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001111866,0.00001231871,0.000001722871,0.00008295511,0.00001478612,3.581693e-7,0.00146405,0.00160182,0.9962338,0.00003988898,0.0002212418,0.0003159458],"study_design_scores_gemma":[0.0002241628,0.00003814922,0.0001542141,0.00001384682,0.00004220715,0.00003254706,0.0001331821,0.005421235,0.9914382,0.000267078,0.002152094,0.00008306566],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9969942,0.000150419,0.001346744,0.0008260202,0.000007988291,0.00004588339,0.00002854821,0.00002279824,0.0005774003],"genre_scores_gemma":[0.9995802,0.00007825401,0.00001722774,0.00004381554,0.0002464103,0.000003277418,0.000006296045,0.000009562396,0.00001492433],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004795576,"threshold_uncertainty_score":0.2598029,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01248604435625442,"score_gpt":0.1994793647536708,"score_spread":0.1869933203974164,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}