{"id":"W3094354114","doi":"10.1016/j.micromeso.2020.110710","title":"Local environment and catalytic property of External Lewis acid sites in hierarchical lamellar titanium Silicalite-1 zeolites","year":2020,"lang":"en","type":"article","venue":"Microporous and Mesoporous Materials","topic":"Zeolite Catalysis and Synthesis","field":"Chemistry","cited_by":16,"is_retracted":false,"has_abstract":false,"ca_institutions":"University of Toronto","funders":"Army Research Laboratory; Army Research Office; National Science Foundation","keywords":"Catalysis; Lamellar structure; Zeolite; Lewis acids and bases; Chemistry; Mesoporous material; Titanium; Inorganic chemistry; Cyclooctene; Brønsted–Lowry acid–base theory; Molecular sieve; Chemical engineering; Organic chemistry; Crystallography","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001304018,0.0001625071,0.0001384314,0.0002193176,0.0001299555,0.0004266198,0.000170492,0.0001548893,0.0005526611],"category_scores_gemma":[0.0002193814,0.0001170505,0.0001228605,0.0001321927,0.0003253732,0.0002273373,0.0001750674,0.000208613,0.000114968],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002559754,"about_ca_system_score_gemma":0.0001212585,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001379516,"about_ca_topic_score_gemma":0.001940761,"domain_scores_codex":[0.9999194,0.00001004426,0.000005503632,0.00001664423,0.00002225825,0.00002607535],"domain_scores_gemma":[0.9998854,0.00002626769,0.00003667902,0.000006635574,0.00002138532,0.00002353711],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002025452,0.00001383739,0.001210278,0.00003382685,0.0000116603,0.00003689639,0.00002613957,0.0002744257,0.997528,0.0001580625,0.0000151545,0.0004891785],"study_design_scores_gemma":[0.00001779409,0.0001109407,0.007154024,0.000003066898,0.00001666181,0.00005071797,0.00009067541,0.002970733,0.9893168,0.00004188874,0.0002177606,0.000008894742],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9995413,0.00007874309,0.0001532358,0.000003979281,9.879469e-7,9.024254e-7,0.00001669662,0.000004835652,0.0001994842],"genre_scores_gemma":[0.9998012,0.00002656505,0.00004080238,0.000001917379,8.263936e-7,6.037837e-7,0.00002313268,0.000001842136,0.0001031914],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001379516,"threshold_uncertainty_score":0.002742946,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01233464067663987,"score_gpt":0.1997803098780172,"score_spread":0.1874456692013773,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}