{"id":"W3095699706","doi":"10.1039/d0sc04611f","title":"A critical analysis of electrospray techniques for the determination of accelerated rates and mechanisms of chemical reactions in droplets","year":2020,"lang":"en","type":"article","venue":"Chemical Science","topic":"Electrohydrodynamics and Fluid Dynamics","field":"Engineering","cited_by":194,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Basic Energy Sciences; Natural Sciences and Engineering Research Council of Canada; U.S. Department of Energy; National Science Foundation","keywords":"Electrospray; Chemistry; Biochemical engineering; Nanotechnology; Chromatography; Mass spectrometry; Materials science; Engineering","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001845825,0.00005994625,0.0001806686,0.0000944174,0.00001478266,0.00000920926,0.0001708373,0.00004891579,0.000002229323],"category_scores_gemma":[0.0004075568,0.00004835326,0.00004232494,0.001444059,0.0002542463,0.00007886848,0.00002873784,0.00008119969,2.026389e-8],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00003257041,"about_ca_system_score_gemma":0.00002141186,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000008736833,"about_ca_topic_score_gemma":0.000002754435,"domain_scores_codex":[0.9993651,0.000003896252,0.0002350387,0.0001319658,0.0001253135,0.0001386985],"domain_scores_gemma":[0.9995053,0.000223278,0.00003393344,0.00008251477,0.0001150122,0.00003989787],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000006734803,0.00001414212,0.00005227386,0.00003801713,0.000009836483,7.773776e-8,0.00004621629,0.00007358015,0.9911014,0.007947585,7.717167e-7,0.0007094091],"study_design_scores_gemma":[0.00002582783,0.00001665176,0.00007289917,0.00000456654,0.00003016459,2.932672e-7,0.000004427446,0.4833646,0.5154895,0.0009650222,5.192753e-7,0.00002544956],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7598396,0.00002981691,0.2397877,0.000164083,0.000006720982,0.0001058281,0.00001163869,0.00001934518,0.00003531739],"genre_scores_gemma":[0.9925454,0.00001984006,0.007395091,0.00001234727,0.000003965814,0.00001417284,0.000004241456,0.00000468417,2.758879e-7],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.4832911,"threshold_uncertainty_score":0.1971789,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01093085480101701,"score_gpt":0.2696952290480651,"score_spread":0.2587643742470481,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}