{"id":"W3097177843","doi":"10.1021/acsomega.0c03764","title":"Probing Electronic Communication and Excited-State Dynamics in the Unprecedented Ferrocene-Containing Zinc MB-DIPY","year":2020,"lang":"en","type":"article","venue":"ACS Omega","topic":"Luminescence and Fluorescent Materials","field":"Materials Science","cited_by":17,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Manitoba","funders":"Natural Sciences and Engineering Research Council of Canada; Minnesota Supercomputing Institute, University of Minnesota; Canada Foundation for Innovation; Western Canada Research Grid; Division of Materials Research; University of Manitoba","keywords":"Ferrocene; Excited state; Photochemistry; Chemistry; Zinc; Electron transfer; BODIPY; Singlet state; Ground state; Quenching (fluorescence); Electrochemistry; Materials science; Atomic physics; Fluorescence; Physical chemistry; Electrode; Physics; Optics; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006203985,0.0001364258,0.0001174677,0.00007314071,0.0001065621,0.0002030326,0.0002316449,0.0001971593,0.0007735666],"category_scores_gemma":[0.0001819602,0.00008563167,0.00005566271,0.00007391451,0.00019642,0.0002371107,0.0001328821,0.0003515666,0.0001056369],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003500501,"about_ca_system_score_gemma":0.0001027027,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007020262,"about_ca_topic_score_gemma":0.0007183504,"domain_scores_codex":[0.9999619,0.000003942531,0.000001208271,0.00001208568,0.00001088102,0.00001011046],"domain_scores_gemma":[0.9999516,0.0000175116,0.00001273298,0.00000402224,0.000005880471,0.000008251409],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00003094343,0.000007495554,0.0001389534,0.00001408422,0.000001418441,0.00002640358,0.00001652124,0.00006054178,0.999032,0.0001210514,0.000008351996,0.0005421079],"study_design_scores_gemma":[0.000006098006,0.0000546611,0.001209468,0.000001487053,0.000002857176,0.0000532335,0.00001248409,0.001506503,0.9968052,0.00003693772,0.0003091787,0.000001976967],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9982297,0.00008529284,0.001356675,0.0000173979,0.000001652195,0.000003758591,0.00003885021,0.00001540271,0.0002513822],"genre_scores_gemma":[0.998094,0.00007670178,0.001281924,0.000006768835,9.42547e-7,0.000005139675,0.00004774041,0.000005958012,0.0004807542],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007735666,"threshold_uncertainty_score":0.002587855,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01759143989087623,"score_gpt":0.2468888887556175,"score_spread":0.2292974488647413,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}