{"id":"W3097706913","doi":"10.1002/anie.202007942","title":"<i>O</i>‐Isocyanates as Uncharged 1,3‐Dipole Equivalents in [3+2] Cycloadditions","year":2020,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Synthesis and Catalytic Reactions","field":"Chemistry","cited_by":16,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"Natural Sciences and Engineering Research Council of Canada; University of Ottawa","keywords":"Oxonium ion; Chemistry; Intramolecular force; Alkene; Cycloaddition; Nitrene; Isocyanate; Intermolecular force; Dipole; Ylide; Computational chemistry; Bond cleavage; Azomethine ylide; Photochemistry; Stereochemistry; 1,3-Dipolar cycloaddition; Molecule; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.0000644146,0.0001653553,0.0001585328,0.00007012582,0.00007117148,0.00006301052,0.000276371,0.0001185057,0.01714957],"category_scores_gemma":[0.0003784837,0.0001778305,0.0001284764,0.0001536339,0.00005246795,0.000343396,0.00006066284,0.0002288669,0.0008084602],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001749743,"about_ca_system_score_gemma":0.00004961406,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001459865,"about_ca_topic_score_gemma":0.00001255198,"domain_scores_codex":[0.9987254,0.000007057732,0.0003170652,0.0003393471,0.000403783,0.0002074088],"domain_scores_gemma":[0.9993771,0.0001096611,0.0001225977,0.0001514864,0.000101014,0.0001380989],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00006667345,0.0002691489,0.001140076,0.00004290203,0.0001105065,0.00003392606,0.0003590863,0.00002737346,0.9328786,0.0007969666,0.06279459,0.001480227],"study_design_scores_gemma":[0.0005521456,0.000010104,0.0005096843,0.00007168806,0.0000201748,0.0000135675,0.0004165207,0.0001155322,0.9149311,0.001224368,0.08195595,0.0001792165],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"other","genre_gemma":"empirical","genre_scores_codex":[0.3867471,0.0002220498,0.0005508681,0.02252834,0.001320491,0.000166132,0.001248968,0.0003636207,0.5868524],"genre_scores_gemma":[0.993687,0.0001237918,0.0000607837,0.001062208,0.001712321,0.00009454118,0.001779908,0.00002452569,0.001454963],"genre_candidate":"empirical","genre_consensus":null,"teacher_disagreement_score":0.6069399,"threshold_uncertainty_score":0.9999695,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.023835196608662,"score_gpt":0.2641990492193436,"score_spread":0.2403638526106816,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}