{"id":"W3099983118","doi":"10.4236/msa.2020.1111050","title":"Polycaprolactone (PCL) Chains Grafting on the Surface of Cellulose Nanocrystals (CNCs) during <i>In Situ</i> Polymerization of <i>ε</i>-Caprolactone at Room Temperature","year":2020,"lang":"en","type":"article","venue":"Materials Sciences and Applications","topic":"Advanced Cellulose Research Studies","field":"Materials Science","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Fonds de recherche du Québec – Nature et technologies; Natural Sciences and Engineering Research Council of Canada; Centre québécois sur les matériaux fonctionnels","keywords":"Polycaprolactone; Cationic polymerization; Polymerization; Materials science; Monomer; Polymer chemistry; Covalent bond; Cellulose; Ring-opening polymerization; Surface modification; X-ray photoelectron spectroscopy; Fourier transform infrared spectroscopy; Grafting; Chemical engineering; In situ polymerization; Nuclear chemistry; Organic chemistry; Chemistry; Polymer; Composite material","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","sts","insufficient_payload"],"consensus_categories":["metaepi_narrow"],"category_scores_codex":[0.003541456,0.001451117,0.002095751,0.0005739411,0.00275705,0.0009316975,0.002339816,0.0005583959,0.001622127],"category_scores_gemma":[0.001286433,0.001165009,0.0003636475,0.003463836,0.00254475,0.001101363,0.001712434,0.0006061418,0.0006600625],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003481955,"about_ca_system_score_gemma":0.0003567731,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0002583911,"about_ca_topic_score_gemma":0.002005729,"domain_scores_codex":[0.9882432,0.001052765,0.002764369,0.002874861,0.002666055,0.002398769],"domain_scores_gemma":[0.9929528,0.001173611,0.002106281,0.002315244,0.0006601901,0.0007918263],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003951377,0.0004774571,0.0004554641,0.0006324581,0.00008006318,0.000001855517,0.003573527,0.001396853,0.9898063,0.002469264,0.0005431724,0.0001684497],"study_design_scores_gemma":[0.001373934,0.0001664698,0.001367182,0.0005919509,0.0001658904,0.00003649389,0.0003065155,0.0000317325,0.932164,0.0005645407,0.06172038,0.001510944],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9805917,0.004320979,0.004812798,0.003305618,0.0004381121,0.003426901,0.001933966,0.0003571905,0.0008127304],"genre_scores_gemma":[0.9800706,0.001990945,0.01119601,0.0002633832,0.0006152011,0.0007194891,0.000699535,0.0001828164,0.00426203],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.06117721,"threshold_uncertainty_score":0.9998239,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03346695724292701,"score_gpt":0.2822980436908397,"score_spread":0.2488310864479127,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}