{"id":"W3099983118","doi":"10.4236/msa.2020.1111050","title":"Polycaprolactone (PCL) Chains Grafting on the Surface of Cellulose Nanocrystals (CNCs) during <i>In Situ</i> Polymerization of <i>ε</i>-Caprolactone at Room Temperature","year":2020,"lang":"en","type":"article","venue":"Materials Sciences and Applications","topic":"Advanced Cellulose Research Studies","field":"Materials Science","cited_by":2,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Fonds de recherche du Québec – Nature et technologies; Natural Sciences and Engineering Research Council of Canada; Centre québécois sur les matériaux fonctionnels","keywords":"Polycaprolactone; Cationic polymerization; Polymerization; Materials science; Monomer; Polymer chemistry; Covalent bond; Cellulose; Ring-opening polymerization; Surface modification; X-ray photoelectron spectroscopy; Fourier transform infrared spectroscopy; Grafting; Chemical engineering; In situ polymerization; Nuclear chemistry; Organic chemistry; Chemistry; Polymer; Composite material","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001519039,0.0001960712,0.0001170921,0.00006468442,0.00007848024,0.0001537913,0.0001278612,0.0001440596,0.0006935707],"category_scores_gemma":[0.0001660532,0.00008598376,0.0001482529,0.00006710242,0.0001326245,0.0001980138,0.00009435539,0.0002457966,0.0001600213],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002109599,"about_ca_system_score_gemma":0.0001628615,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0006349882,"about_ca_topic_score_gemma":0.001098079,"domain_scores_codex":[0.9998988,0.000009720733,0.000005697443,0.00003169788,0.00002964237,0.00002436954],"domain_scores_gemma":[0.9998902,0.00002855552,0.00003768404,0.00001009713,0.00001933571,0.00001416932],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001863144,0.000005074778,0.00004387812,0.00001620709,0.000001215816,0.00002308482,0.0000112675,0.00004685533,0.9993414,0.00002187151,0.000005896588,0.0004647227],"study_design_scores_gemma":[0.000001073243,0.00003081174,0.0003897737,9.14641e-7,0.000001693421,0.00002202081,0.000004841363,0.0001905941,0.9992025,0.000004453774,0.0001503277,0.000001019965],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9954656,0.0003122241,0.002961793,0.00002693308,0.00001397094,0.00001235992,0.0000517209,0.00002720205,0.001128337],"genre_scores_gemma":[0.9956539,0.0002455647,0.00245019,0.00002249708,0.000005295292,0.00001127696,0.00006992969,0.00001339368,0.001527927],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0006935707,"threshold_uncertainty_score":0.00232017,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03346695724292701,"score_gpt":0.2822980436908397,"score_spread":0.2488310864479127,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}