{"id":"W3100974888","doi":"10.1093/oso/9780190200794.003.0054","title":"C–N Ring Construction: The Harrity Synthesis of Quinolizidine (–)-217A","year":2015,"lang":"en","type":"book-chapter","venue":"Oxford University Press eBooks","topic":"Synthesis and Catalytic Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Pyrrolidine; Metathesis; Enantioselective synthesis; Annulation; Catalysis; Organic chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002452303,0.0003218517,0.0002226848,0.0002960655,0.0003084072,0.0002169423,0.0005469303,0.0002431814,0.002388411],"category_scores_gemma":[0.0001795367,0.0001324378,0.0002445749,0.0001421366,0.0002407927,0.0003610771,0.000448075,0.0004575111,0.001359046],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003509011,"about_ca_system_score_gemma":0.0002872953,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0005611213,"about_ca_topic_score_gemma":0.0009658981,"domain_scores_codex":[0.9998896,0.00002033341,0.000007602293,0.00002662973,0.00002165537,0.00003404192],"domain_scores_gemma":[0.9999528,0.00000387619,0.00001061913,0.00000813191,0.00001048739,0.00001404133],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002225888,0.0002698577,0.0005313138,0.0005914619,0.00007208979,0.001557881,0.0003525393,0.001844345,0.8960887,0.01735751,0.004132426,0.07697932],"study_design_scores_gemma":[0.0001290371,0.002503023,0.002248422,0.0000605076,0.00005337547,0.002126555,0.00008683099,0.00317509,0.8688154,0.00317109,0.1175566,0.00007422021],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.7737526,0.01567786,0.09905454,0.002838239,0.001340857,0.001172723,0.001481676,0.001203459,0.103478],"genre_scores_gemma":[0.9620051,0.004679221,0.01873312,0.0003364828,0.00006426033,0.0001285617,0.0003379202,0.00005536101,0.01365996],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002388411,"threshold_uncertainty_score":0.007990062,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.04018760894313901,"score_gpt":0.2103893398918983,"score_spread":0.1702017309487593,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}