{"id":"W3101043770","doi":"10.1093/oso/9780199965724.003.0055","title":"C-N Ring Construction: The Zakarian Synthesis of (-)-Rhazinilam","year":2013,"lang":"en","type":"book-chapter","venue":"Oxford University Press eBooks","topic":"Alkaloids: synthesis and pharmacology","field":"Pharmacology, Toxicology and Pharmaceutics","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Enantiomer; Aziridine; Imine; Chemistry; Enantioselective synthesis; Malonate; Stereochemistry; Ring (chemistry); Catalysis; Organic chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0004374682,0.0005338711,0.0007517472,0.0001929878,0.0005856242,0.00002460384,0.001015359,0.001189455,0.004988496],"category_scores_gemma":[0.00003253499,0.000478885,0.0004267554,0.00001925603,0.001471022,0.00009733625,0.0004533052,0.001577128,0.00002952098],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001351157,"about_ca_system_score_gemma":0.0001724165,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00005484546,"about_ca_topic_score_gemma":0.0000140762,"domain_scores_codex":[0.9978978,0.0003759684,0.0004768,0.0005251178,0.0002457352,0.0004785953],"domain_scores_gemma":[0.9969835,0.001303131,0.0007146054,0.0005385045,0.0002203731,0.0002399334],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"theoretical_or_conceptual","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0005168833,0.00005291067,0.00004986245,0.0001860889,0.001762128,0.00009374297,0.0003397064,0.00004684029,0.001220353,0.8987823,0.01362977,0.08331949],"study_design_scores_gemma":[0.0006158806,0.00006264669,0.00002924234,0.0000753995,0.001477766,0.00004966866,0.0001064677,0.000146522,0.008076132,0.0009506523,0.9879543,0.0004553685],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"other","genre_gemma":"other","genre_scores_codex":[0.001091369,0.0002816167,0.00005395488,0.0002048706,0.001366921,0.0007553475,0.0002680844,0.0001073435,0.9958705],"genre_scores_gemma":[0.02646802,0.001732208,0.0002617433,0.0003461527,0.0004791387,0.00001142825,0.00001580094,0.00008097971,0.9706045],"genre_candidate":"other","genre_consensus":"other","teacher_disagreement_score":0.9743245,"threshold_uncertainty_score":0.9997663,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.08354946886476297,"score_gpt":0.3117595326811794,"score_spread":0.2282100638164164,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}