{"id":"W3101906693","doi":"10.1002/anie.202015036","title":"Cationic Boron Formazanate Dyes**","year":2020,"lang":"en","type":"article","venue":"Angewandte Chemie International Edition","topic":"Luminescence and Fluorescent Materials","field":"Materials Science","cited_by":22,"is_retracted":false,"has_abstract":true,"ca_institutions":"Western University","funders":"Ontario Ministry of Research and Innovation; Natural Sciences and Engineering Research Council of Canada; Ontario Ministry of Research, Innovation and Science","keywords":"Boron; Cationic polymerization; Conjugated system; Density functional theory; Absorption spectroscopy; Atom (system on chip); Spectroscopy; Photochemistry; Materials science; Reactivity (psychology); Absorption (acoustics); Chemistry; Computational chemistry; Chemical physics; Organic chemistry; Polymer chemistry; Polymer; Physics; Optics; Computer science","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":["insufficient_payload"],"category_scores_codex":[0.000130458,0.0001218062,0.0001202775,0.00003423885,0.00007700462,0.0001304739,0.0003014571,0.00006490057,0.003748492],"category_scores_gemma":[0.0001222485,0.0001145312,0.00005453786,0.00006449773,0.0000500204,0.0007243741,0.00006993154,0.00006304067,0.001162049],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00007789403,"about_ca_system_score_gemma":0.00003746045,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003532628,"about_ca_topic_score_gemma":0.000005416007,"domain_scores_codex":[0.9989132,0.00001403856,0.0002656947,0.0002608554,0.0003612999,0.0001849009],"domain_scores_gemma":[0.9994701,0.00002054948,0.0001286847,0.000110831,0.0001672662,0.000102582],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004862055,0.00002861576,0.0002035605,0.00001961907,0.000007422839,0.000005160708,0.0002908266,0.000005128862,0.9619585,0.0004597016,0.0367871,0.0001857017],"study_design_scores_gemma":[0.0003597075,0.00003189952,0.0004745076,0.00002400065,0.00001040638,0.000005975517,0.00005665476,0.0001319613,0.975325,0.0003993702,0.02304587,0.0001346139],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9190676,0.0001346725,0.01074344,0.02944709,0.009006449,0.000490393,0.0005257275,0.0006122895,0.02997237],"genre_scores_gemma":[0.9939982,0.00005570343,0.000352716,0.002033805,0.002779932,0.00003332565,0.000509993,0.00001418536,0.0002221443],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.07493063,"threshold_uncertainty_score":0.9996157,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02043988173122395,"score_gpt":0.2533135825693163,"score_spread":0.2328737008380923,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}