{"id":"W3102008574","doi":"10.1093/oso/9780190646165.003.0091","title":"The Deslongchamps Synthesis of (+)-Cassaine","year":2017,"lang":"en","type":"book-chapter","venue":"Oxford University Press eBooks","topic":"Biological Stains and Phytochemicals","field":"Medicine","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Enone; Chemistry; Intramolecular force; Ketone; Sulfoxide; Michael reaction; Amide; Stereochemistry; Medicinal chemistry; Organic chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00013929,0.0002285442,0.0004937182,0.00003413403,0.0002826746,0.00001536532,0.0004305278,0.0004490372,0.00004924909],"category_scores_gemma":[0.00007924568,0.0001528643,0.0003109238,0.000002003034,0.0006006302,0.00001506613,0.00028926,0.0003690294,6.242471e-7],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00006335788,"about_ca_system_score_gemma":0.00006270448,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00003399267,"about_ca_topic_score_gemma":0.000007681444,"domain_scores_codex":[0.9991496,0.00001885553,0.0001697917,0.000260332,0.0001946536,0.000206794],"domain_scores_gemma":[0.9983499,0.0002991374,0.0003279566,0.0007441967,0.0001472936,0.0001315267],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"theoretical_or_conceptual","study_design_gemma":"not_applicable","study_design_scores_codex":[0.001170021,0.00003222799,0.00003714052,0.0002376984,0.0006586353,0.0002116752,0.00003629887,1.529914e-7,0.0005902471,0.8853217,0.003640408,0.1080637],"study_design_scores_gemma":[0.0003086354,0.0001112548,0.0000528721,0.0002860087,0.0003109586,0.00001044622,0.000009684392,0.000003981861,0.002191078,0.001507751,0.9950467,0.0001606001],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"other","genre_gemma":"other","genre_scores_codex":[0.0002586876,0.000234909,0.0000282779,0.0001080975,0.00005082085,0.0003574387,0.00009566232,0.00003236644,0.9988337],"genre_scores_gemma":[0.01598788,0.001172404,0.0001239914,0.0000321469,0.0001010541,0.000001103745,0.00001251248,0.00002071885,0.9825482],"genre_candidate":"other","genre_consensus":"other","teacher_disagreement_score":0.9914063,"threshold_uncertainty_score":0.6233627,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03879777922709369,"score_gpt":0.2348127449076085,"score_spread":0.1960149656805148,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}