{"id":"W3102785348","doi":"10.1093/oso/9780190200794.003.0032","title":"Synthesis and Reactions of Alkenes","year":2015,"lang":"en","type":"book-chapter","venue":"Oxford University Press eBooks","topic":"Chemical Synthesis and Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Hydroamination; Allylic rearrangement; Chemistry; Photoredox catalysis; Markovnikov's rule; Trifluoromethylation; Catalysis; Organic chemistry; Medicinal chemistry; Regioselectivity; Trifluoromethyl; Photocatalysis","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000635414,0.0009664688,0.0005908672,0.0009098636,0.0008282709,0.0006053229,0.000767329,0.0008007761,0.007191254],"category_scores_gemma":[0.0003415748,0.0005890721,0.0004843809,0.0007751125,0.0004302828,0.001457821,0.001066803,0.002365801,0.007165458],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0008075329,"about_ca_system_score_gemma":0.0006217746,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0004104236,"about_ca_topic_score_gemma":0.001143492,"domain_scores_codex":[0.9992318,0.00007443533,0.00008072954,0.0001596676,0.0002554359,0.0001979641],"domain_scores_gemma":[0.9998397,0.0000163845,0.00002383858,0.00003354106,0.0000589474,0.00002751114],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0002399794,0.0003183619,0.000362609,0.002860941,0.00009083815,0.0009898456,0.0008380478,0.001447588,0.7939557,0.06426294,0.01355429,0.1210787],"study_design_scores_gemma":[0.00002843238,0.000305282,0.0001721024,0.00009918303,0.00001638665,0.0003400106,0.00006309426,0.0002560033,0.7644017,0.002106352,0.232155,0.00005642098],"study_design_candidate":"not_applicable","study_design_consensus":null,"genre_codex":"other","genre_gemma":"other","genre_scores_codex":[0.2626598,0.1994743,0.2201634,0.004497069,0.007112238,0.002635553,0.01065858,0.003040893,0.2897582],"genre_scores_gemma":[0.6707667,0.1134087,0.08075117,0.001324841,0.0003509586,0.001497869,0.00529761,0.000551703,0.1260505],"genre_candidate":"other","genre_consensus":"other","teacher_disagreement_score":0.007191254,"threshold_uncertainty_score":0.02405709,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.03512331961666878,"score_gpt":0.2077446719273901,"score_spread":0.1726213523107213,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}