{"id":"W3104472735","doi":"10.1093/oso/9780199764549.003.0016","title":"Functionalization of C-H Bonds: The Baran Synthesis of Dihydroxyeudesmane","year":2011,"lang":"en","type":"book-chapter","venue":"Oxford University Press eBooks","topic":"Oxidative Organic Chemistry Reactions","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"","keywords":"Chemistry; Intramolecular force; Adamantane; Medicinal chemistry; Catalysis; Amination; Stereochemistry; Organic chemistry","routes":{"ca_aff":false,"ca_fund":false,"ca_venue":false,"about_ca":true,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow","insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.00006158849,0.0002734725,0.0003723947,0.00006198385,0.0001088869,0.000005765929,0.000502735,0.0003774123,0.001907085],"category_scores_gemma":[0.00003062136,0.0002643644,0.000211392,0.00001169699,0.0004134494,0.00004021538,0.0002132755,0.0003018487,0.000001004608],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001176172,"about_ca_system_score_gemma":0.0001028573,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000617511,"about_ca_topic_score_gemma":0.000009730478,"domain_scores_codex":[0.9989972,0.0000122591,0.0002719221,0.0003004088,0.0002822003,0.0001360057],"domain_scores_gemma":[0.998225,0.000195985,0.0006195502,0.000693531,0.0002060856,0.00005985006],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"theoretical_or_conceptual","study_design_gemma":"not_applicable","study_design_scores_codex":[0.0004861076,0.0001467721,0.00007623029,0.001684707,0.002116185,0.00002739627,0.0005801393,0.00002715121,0.1601405,0.8267199,0.003335756,0.004659166],"study_design_scores_gemma":[0.0001823482,0.00001103966,0.000005274484,0.0002249383,0.0005478617,0.000007429676,0.00005533512,0.0000127185,0.2434144,0.000428058,0.7549126,0.0001980697],"study_design_candidate":"theoretical_or_conceptual","study_design_consensus":null,"genre_codex":"other","genre_gemma":"other","genre_scores_codex":[0.0007688718,0.0000449213,0.0001184215,0.000009062492,0.00003838003,0.00009092774,0.0005251047,0.00004952376,0.9983548],"genre_scores_gemma":[0.06497883,0.0001431837,0.00004146792,0.000003450956,0.00006374983,0.000001186618,0.00007727736,0.00004644101,0.9346444],"genre_candidate":"other","genre_consensus":"other","teacher_disagreement_score":0.8262919,"threshold_uncertainty_score":0.9999809,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02343626357951669,"score_gpt":0.1858474562035039,"score_spread":0.1624111926239872,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}