{"id":"W3104926628","doi":"10.1021/acs.inorgchem.0c02783","title":"Reactions of Molybdenum and Tungsten Oxide Tetrafluoride with Sulfur(IV) Lewis Bases: Structure and Bonding in [WOF<sub>4</sub>]<sub>4</sub>, MOF<sub>4</sub>(OSO), and [SF<sub>3</sub>][M<sub>2</sub>O<sub>2</sub>F<sub>9</sub>] (M = Mo, W)","year":2020,"lang":"en","type":"article","venue":"Inorganic Chemistry","topic":"Inorganic Fluorides and Related Compounds","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Lethbridge","funders":"Natural Sciences and Engineering Research Council of Canada; Government of Canada","keywords":"Chemistry; Hexacoordinate; Crystallography; Molybdenum; Crystal structure; Tungsten; Inorganic chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006878576,0.0002505006,0.0001741044,0.00008038487,0.0001364102,0.0001523017,0.000370958,0.0002600892,0.001231037],"category_scores_gemma":[0.0001359351,0.0001149191,0.0001349122,0.0001169318,0.0002189269,0.0002308688,0.0002423777,0.0001759964,0.0001527289],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002943105,"about_ca_system_score_gemma":0.0001478244,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00205681,"about_ca_topic_score_gemma":0.00311025,"domain_scores_codex":[0.9999493,0.000005631039,0.000002633513,0.00000968762,0.0000121602,0.00002059587],"domain_scores_gemma":[0.9999717,0.000005435317,0.00001117578,0.000002517025,0.000003713889,0.000005401615],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000836637,0.00003291411,0.001483871,0.0001567787,0.00003839838,0.000182228,0.0001430346,0.00170916,0.9890441,0.0007170598,0.0001812415,0.005474504],"study_design_scores_gemma":[0.00003759473,0.000363256,0.002856554,0.000009241541,0.00001921842,0.0001258807,0.0001117369,0.002846606,0.9915508,0.0002019377,0.001866139,0.0000109544],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9991918,0.0001805806,0.0002028329,0.00001252351,0.000002532342,0.000002625909,0.00004633945,0.00001140964,0.0003493217],"genre_scores_gemma":[0.9990944,0.0001657058,0.0002054664,0.000006240266,0.000001100053,0.000003531744,0.00008392021,0.000005505,0.0004341163],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00205681,"threshold_uncertainty_score":0.004118264,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.006819551335251609,"score_gpt":0.1848930903127277,"score_spread":0.1780735389774761,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}