{"id":"W3105869102","doi":"10.1071/ch20256","title":"Immobilisation of Homogeneous Pd Catalysts within a Type I Porous Liquid*","year":2020,"lang":"en","type":"article","venue":"Australian Journal of Chemistry","topic":"Catalytic Cross-Coupling Reactions","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"St. Thomas University","funders":"","keywords":"Catalysis; Porosity; Chemistry; Heck reaction; Ionic liquid; Palladium; Chemical engineering; Homogeneous; Carbene; Homogeneous catalysis; Green chemistry; Heterogeneous catalysis; Porous medium; Organic chemistry; Thermodynamics","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.000119194,0.0002481243,0.0002227757,0.0002057868,0.0001325356,0.0004198656,0.0003805819,0.0002496454,0.0006702901],"category_scores_gemma":[0.0002082388,0.0001487212,0.0002321889,0.0001253801,0.0003213339,0.0003094825,0.0003311043,0.0003619367,0.0003076345],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004599333,"about_ca_system_score_gemma":0.0002746984,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001044293,"about_ca_topic_score_gemma":0.001573606,"domain_scores_codex":[0.9998678,0.000009523127,0.000008609542,0.00004310773,0.00003271233,0.00003825929],"domain_scores_gemma":[0.9998947,0.00002689635,0.0000322997,0.00001369804,0.00001592189,0.0000164331],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002533871,0.000006260399,0.0000430423,0.00002262881,0.000003147743,0.00003839054,0.00001244714,0.00008007787,0.9983557,0.0001432057,0.0000181356,0.001251608],"study_design_scores_gemma":[0.000002692813,0.00004746479,0.0001228467,0.000001541114,0.000004549752,0.00003189621,0.000005397927,0.0004820085,0.9986678,0.00001487307,0.0006168596,0.000001997809],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9709844,0.0008029956,0.02378071,0.00008585936,0.00003369189,0.0000468546,0.0001579771,0.0003024695,0.003805023],"genre_scores_gemma":[0.9903618,0.0002864438,0.007191963,0.00002182895,0.000007877367,0.00001650747,0.0001357788,0.0000396002,0.001938242],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001044293,"threshold_uncertainty_score":0.003337085,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.02829585893022556,"score_gpt":0.268394960081995,"score_spread":0.2400991011517694,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}