{"id":"W3105946483","doi":"10.1055/s-0040-1707314","title":"Synthesis of Azido Acids and Their Application in the Preparation of Complex Peptides","year":2020,"lang":"en","type":"article","venue":"Synthesis","topic":"Chemical Synthesis and Analysis","field":"Biochemistry, Genetics and Molecular Biology","cited_by":4,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Natural Sciences and Engineering Research Council of Canada; Government of Ontario","keywords":"Chemistry; Synthon; Azide; Moiety; Amino acid; Peptide synthesis; Combinatorial chemistry; Protecting group; Peptide; Total synthesis; Electrophile; Organic chemistry; Stereochemistry; Catalysis; Biochemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002064192,0.00009557787,0.0002150195,0.00002204817,0.00002334744,0.000007014928,0.000179557,0.00006769119,0.00001459125],"category_scores_gemma":[0.0004508254,0.00006408671,0.00009702684,0.0001337796,0.0000963728,0.000003261989,0.00004494271,0.00002965794,0.000001147885],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000003296813,"about_ca_system_score_gemma":0.00001072701,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004166851,"about_ca_topic_score_gemma":0.000024947,"domain_scores_codex":[0.9992906,0.0000889453,0.0002445023,0.0002061861,0.00008529073,0.00008440715],"domain_scores_gemma":[0.9993974,0.0001993877,0.0001226423,0.0002196236,0.00003281816,0.00002815239],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005319611,0.00004657635,0.004237539,0.0000496142,0.00004135792,6.408356e-8,0.0002071065,0.00001457708,0.9764889,0.00005829225,0.0001130291,0.01868976],"study_design_scores_gemma":[0.00004611642,0.00003404309,0.006353616,0.00001559322,0.00004026641,7.310323e-7,0.0004826355,0.0007934614,0.9901897,0.0000689783,0.001901053,0.00007381255],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9968065,0.0002308145,0.0008718652,0.001025622,0.00000210391,0.000117725,0.00003288797,0.000003629981,0.0009088631],"genre_scores_gemma":[0.9993491,0.0001443147,0.0003015386,0.00009256176,0.00003976605,0.00005118488,0.00001091665,0.000007401045,0.000003230975],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.01861594,"threshold_uncertainty_score":0.261338,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01436205695316007,"score_gpt":0.2501114031593318,"score_spread":0.2357493462061718,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}