{"id":"W3106898048","doi":"10.1002/macp.202000321","title":"Examining the Spin State and Redox Chemistry of Ni(Diimine) Catalysts during the Synthesis of π‐Conjugated Polymers","year":2020,"lang":"en","type":"article","venue":"Macromolecular Chemistry and Physics","topic":"Organometallic Complex Synthesis and Catalysis","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Sciences and Engineering Research Council of Canada; Compute Canada; Ontario Centres of Excellence","keywords":"Diimine; Polymerization; Chemistry; Photochemistry; Monomer; Catalysis; Polymer chemistry; Phosphine; Conjugated system; Polymer; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001170284,0.0002780646,0.0004296386,0.00000339869,0.0001524835,0.00004058533,0.0003791197,0.00007964593,0.0008822927],"category_scores_gemma":[0.0001300811,0.0002057878,0.0001314122,0.0002360494,0.0004291621,0.00004389511,0.0002798054,0.0002156606,0.000001052999],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001236767,"about_ca_system_score_gemma":0.00003647929,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004444926,"about_ca_topic_score_gemma":4.420931e-7,"domain_scores_codex":[0.9986634,0.00002468552,0.0004067945,0.0004051279,0.0002602079,0.0002398385],"domain_scores_gemma":[0.9988029,0.000152045,0.00032614,0.0005540099,0.00004906083,0.0001158477],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004445087,0.00003626488,0.0004317886,0.001324526,0.000312197,0.00001138285,0.0006167159,0.000009635536,0.9885581,0.000004068192,0.000005919056,0.008645002],"study_design_scores_gemma":[0.0002285697,0.000005317369,0.0003994548,0.00008830371,0.0002462124,0.00002172115,0.0007488607,0.0002987831,0.9975222,0.00003555155,0.0001885386,0.0002164724],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9943159,0.0009708934,0.00003105047,0.0002483184,0.000005362144,0.00004811704,0.0001345872,0.00001930309,0.004226453],"genre_scores_gemma":[0.9991484,0.0001276496,0.00003178632,0.00002905563,0.00007910071,0.00001400565,0.00002471485,0.00003327461,0.0005120633],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.008964166,"threshold_uncertainty_score":0.9660487,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01016517323216855,"score_gpt":0.1955279313714946,"score_spread":0.185362758139326,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}