{"id":"W3107649180","doi":"10.1021/jacs.0c10632","title":"Interfacial Field-Driven Proton-Coupled Electron Transfer at Graphite-Conjugated Organic Acids","year":2020,"lang":"en","type":"article","venue":"Journal of the American Chemical Society","topic":"Porphyrin and Phthalocyanine Chemistry","field":"Materials Science","cited_by":67,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Air Force Office of Scientific Research; National Institute of General Medical Sciences; Canadian Institute for Advanced Research; Research Corporation for Science Advancement; Basic Energy Sciences; Alfred P. Sloan Foundation","keywords":"Chemistry; Electron transfer; Cyclic voltammetry; Proton-coupled electron transfer; Redox; Chemical physics; Graphite; Conjugated system; Photochemistry; Electrochemistry; Organic chemistry; Physical chemistry; Electrode","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001479933,0.0001879982,0.0004167419,0.000006698289,0.00009333833,0.00003193865,0.0007735837,0.00007960042,0.0006495346],"category_scores_gemma":[0.000120168,0.0001252745,0.0005587427,0.0003584867,0.0002885303,0.0000822599,0.0001590508,0.000533666,0.00001838218],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001337739,"about_ca_system_score_gemma":0.0001032177,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001000601,"about_ca_topic_score_gemma":3.742203e-7,"domain_scores_codex":[0.9986174,0.00004521627,0.0004301222,0.0002080232,0.0003789944,0.0003203096],"domain_scores_gemma":[0.999119,0.00007224279,0.0003158817,0.0001822648,0.0000996437,0.0002109954],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.000323317,0.00004545641,0.00219849,0.00003007281,0.00005196224,0.000003855117,0.0006239014,0.000005915045,0.9937934,0.000001287622,0.002898805,0.00002349625],"study_design_scores_gemma":[0.0005619672,0.0002213869,0.0001956578,0.00002307039,0.00005177936,0.00007991443,0.00008233554,0.0001380493,0.9972693,0.00002872954,0.0011915,0.0001562825],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9944492,0.0000384458,0.0001973991,0.004983573,0.0001010921,0.0001340685,0.000007521205,0.00003007496,0.00005864333],"genre_scores_gemma":[0.9961643,0.0000356261,0.0003258199,0.003018531,0.0003971646,0.000004806126,0.000001163499,0.00002046718,0.0000321224],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.003475886,"threshold_uncertainty_score":0.7111948,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009418906276668566,"score_gpt":0.2342081877652877,"score_spread":0.2247892814886192,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}