{"id":"W3107718749","doi":"10.1039/d0sc06466a","title":"Activation of ammonia and hydrazine by electron rich Fe( <scp>ii</scp> ) complexes supported by a dianionic pentadentate ligand platform through a common terminal Fe( <scp>iii</scp> ) amido intermediate","year":2020,"lang":"en","type":"article","venue":"Chemical Science","topic":"Ammonia Synthesis and Nitrogen Reduction","field":"Chemical Engineering","cited_by":36,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"Natural Sciences and Engineering Research Council of Canada; National Institutes of Health; Institut Universitaire de France; China Scholarship Council; Alberta Innovates; National Institute of General Medical Sciences; Centre National de la Recherche Scientifique; Alberta Innovates - Technology Futures","keywords":"Chemistry; Hydrazine (antidepressant); Ligand (biochemistry); Ammonia; Adduct; Dimer; Cationic polymerization; Hydrogen bond; Coordination complex; Medicinal chemistry; Inorganic chemistry; Crystallography; Photochemistry; Molecule; Metal; Polymer chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["metaepi_narrow"],"consensus_categories":[],"category_scores_codex":[0.0002107051,0.0003737861,0.0005276602,0.00006929045,0.0002386329,0.000103785,0.000588096,0.0001747992,0.000006578678],"category_scores_gemma":[0.0004905019,0.000345163,0.00009985865,0.0008265638,0.0007653649,0.0008112655,0.0003292252,0.000465802,0.00001204912],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002212381,"about_ca_system_score_gemma":0.00007108065,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001198355,"about_ca_topic_score_gemma":0.00000353848,"domain_scores_codex":[0.9972166,0.00001735668,0.0005877065,0.0007415883,0.0006520983,0.0007846372],"domain_scores_gemma":[0.9986209,0.0003192729,0.000330471,0.0002403823,0.00008363985,0.0004053208],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002108879,0.0001278117,0.0006515267,0.00006881919,0.00002849225,0.000002629125,0.00129882,0.000004461735,0.9940835,0.0000503835,0.002939894,0.0007225252],"study_design_scores_gemma":[0.0006950769,0.0001678975,0.000482399,0.00007286828,0.00004898728,0.00003063467,0.000461537,0.004974257,0.9915409,0.0001425877,0.001267605,0.0001152302],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9982939,0.0003307528,0.000383365,0.0002313072,0.00005877892,0.0002766364,0.00004991798,0.0001290708,0.0002462091],"genre_scores_gemma":[0.9990281,0.0001238594,0.0002835024,0.0001511709,0.0001093201,0.00003153878,0.0001190061,0.0000372254,0.0001162649],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.004969795,"threshold_uncertainty_score":0.9999,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01297616562862468,"score_gpt":0.2434816939954467,"score_spread":0.230505528366822,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}