{"id":"W3107718749","doi":"10.1039/d0sc06466a","title":"Activation of ammonia and hydrazine by electron rich Fe( <scp>ii</scp> ) complexes supported by a dianionic pentadentate ligand platform through a common terminal Fe( <scp>iii</scp> ) amido intermediate","year":2020,"lang":"en","type":"article","venue":"Chemical Science","topic":"Ammonia Synthesis and Nitrogen Reduction","field":"Chemical Engineering","cited_by":36,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Calgary","funders":"Natural Sciences and Engineering Research Council of Canada; National Institutes of Health; Institut Universitaire de France; China Scholarship Council; Alberta Innovates; National Institute of General Medical Sciences; Centre National de la Recherche Scientifique; Alberta Innovates - Technology Futures","keywords":"Chemistry; Hydrazine (antidepressant); Ligand (biochemistry); Ammonia; Adduct; Dimer; Cationic polymerization; Hydrogen bond; Coordination complex; Medicinal chemistry; Inorganic chemistry; Crystallography; Photochemistry; Molecule; Metal; Polymer chemistry; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00004433655,0.0001806405,0.00007411369,0.00004113642,0.00007585794,0.00009207674,0.0001561915,0.0001787348,0.001422952],"category_scores_gemma":[0.00007408457,0.00006421805,0.00007420902,0.000044327,0.00009800935,0.0001245999,0.0001764728,0.0001903264,0.0002129198],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001175232,"about_ca_system_score_gemma":0.00008179693,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003284775,"about_ca_topic_score_gemma":0.001298483,"domain_scores_codex":[0.9999616,0.000005132324,0.000001746778,0.000009287298,0.000009109125,0.00001313472],"domain_scores_gemma":[0.9999878,0.0000022816,0.000003582962,0.000001843602,0.000001784184,0.000002702983],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0001263331,0.00001933973,0.0001550345,0.0001353903,0.00001208912,0.0001302416,0.00003992542,0.000220092,0.9938307,0.0009100397,0.0003695854,0.00405132],"study_design_scores_gemma":[0.0000115781,0.0001432943,0.0007408864,0.000005411229,0.000005931402,0.0001233151,0.00001837637,0.00120687,0.9946138,0.0000976506,0.003029022,0.000003765417],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9868134,0.0006960153,0.003253017,0.0001050181,0.00004463306,0.00002549769,0.00009767555,0.00007104944,0.008893766],"genre_scores_gemma":[0.9973717,0.0001848521,0.0008309915,0.00001625744,0.000003123869,0.000007029545,0.00005385138,0.000006065502,0.001526108],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001422952,"threshold_uncertainty_score":0.004760206,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01297616562862468,"score_gpt":0.2434816939954467,"score_spread":0.230505528366822,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}