{"id":"W3107808094","doi":"10.1021/acs.energyfuels.0c02908","title":"Sulfided Homogeneous Iron Precatalyst for Partial Hydrogenation and Hydrodesulfurization of Polycyclic Aromatic Model Asphaltenes","year":2020,"lang":"en","type":"article","venue":"Energy & Fuels","topic":"Catalysis and Hydrodesulfurization Studies","field":"Engineering","cited_by":7,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Alberta","funders":"University of Alberta","keywords":"Benzothiophene; Catalysis; Chemistry; Dibenzothiophene; Hydrodesulfurization; Thermogravimetric analysis; Phenanthrene; Naphthalene; Sulfide; Sulfidation; Temperature-programmed reduction; Organic chemistry; Inorganic chemistry; Thiophene","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0000755504,0.0001941586,0.000340323,0.00009403872,0.00008729745,0.0000278904,0.00009726501,0.00007570755,0.000003798918],"category_scores_gemma":[0.00005457664,0.0002000517,0.00009381066,0.0002488719,0.00004408655,0.0001621018,0.00003554168,0.00003426868,0.000002124294],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00001994506,"about_ca_system_score_gemma":0.00001492319,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00001386022,"about_ca_topic_score_gemma":0.00002313702,"domain_scores_codex":[0.9989037,0.00001624189,0.0004471903,0.0002601504,0.0001781012,0.0001946412],"domain_scores_gemma":[0.9995424,0.00005796614,0.0001086105,0.0001671792,0.00002568438,0.00009816579],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"simulation_or_modeling","study_design_scores_codex":[0.00003504354,0.00003382531,0.00007011185,0.0001774833,0.0001691495,8.160753e-7,0.0009560708,0.3901999,0.6010654,0.0009094765,0.0001963304,0.006186407],"study_design_scores_gemma":[0.0003848569,0.00003529787,0.00003619703,0.00001190539,0.0001008917,0.000001596812,0.00002377176,0.5264893,0.4717226,0.0005536387,0.000480395,0.0001595946],"study_design_candidate":"bench_or_experimental","study_design_consensus":null,"genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8469961,0.001919798,0.1499932,0.0001648321,0.00007732928,0.0001723764,0.00004797627,0.0001919769,0.0004363891],"genre_scores_gemma":[0.9980723,0.0004620031,0.0008460709,0.00007277569,0.0001262798,0.00008690339,0.0002139273,0.00004810606,0.00007161594],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1510762,"threshold_uncertainty_score":0.815787,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01592676609748425,"score_gpt":0.2112794940636113,"score_spread":0.195352727966127,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}