{"id":"W3107834723","doi":"10.1021/acs.jpcb.0c09523","title":"Active-Site Environmental Factors Customize the Photophysics of Photoenzymatic Old Yellow Enzymes","year":2020,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry B","topic":"Photosynthetic Processes and Mechanisms","field":"Biochemistry, Genetics and Molecular Biology","cited_by":18,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"National Renewable Energy Laboratory; Basic Energy Sciences; Canadian Network for Research and Innovation in Machining Technology, Natural Sciences and Engineering Research Council of Canada; Searle Scholars Program; National Institute of General Medical Sciences; Canadian Institute for Advanced Research; National Institutes of Health; National Science Foundation","keywords":"Active site; Electron transfer; Photoinduced electron transfer; Chemistry; Redox; Enzyme; Electron transport chain; Biophysics; Photochemistry; Biochemistry; Biology; Organic chemistry","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001569918,0.0001799763,0.0001415407,0.00008055492,0.0000904097,0.0002887014,0.0001731273,0.0001703883,0.0006929358],"category_scores_gemma":[0.0002765497,0.0001075828,0.0000947074,0.00008630751,0.0002110229,0.0003601515,0.0001858797,0.0004478838,0.0001246599],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001914766,"about_ca_system_score_gemma":0.00008335403,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0001922856,"about_ca_topic_score_gemma":0.0002906997,"domain_scores_codex":[0.9999396,0.000009978811,0.000003931465,0.00001978518,0.00001476115,0.00001198294],"domain_scores_gemma":[0.9998906,0.00004321661,0.00002804234,0.00001304555,0.000009375117,0.00001577549],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002199763,0.000008268778,0.0003389834,0.00001074847,0.000001678479,0.00001090116,0.00001398216,0.00009905757,0.9989518,0.0001110793,0.000004819072,0.0004267023],"study_design_scores_gemma":[0.000005078851,0.00005840063,0.00615208,0.000001689967,0.000005675623,0.00008038162,0.00004413001,0.002054252,0.9909039,0.000156952,0.0005323542,0.000005186036],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9964325,0.0001291777,0.003078426,0.00002272554,0.000003648463,0.000004608436,0.00003629361,0.00001762982,0.0002748684],"genre_scores_gemma":[0.9983892,0.00009687927,0.001198536,0.000008024925,0.000001078408,0.0000048687,0.0000454796,0.00001203425,0.000243972],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0006929358,"threshold_uncertainty_score":0.002318084,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.007322623447344689,"score_gpt":0.2039053172206899,"score_spread":0.1965826937733453,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}