{"id":"W3109831498","doi":"10.1021/acsabm.0c00918","title":"Selective Crystal Growth Regulation by Chiral α-Hydroxycarboxylic Acids Improves the Strength and Toughness of Calcium Sulfate Cements","year":2020,"lang":"en","type":"article","venue":"ACS Applied Bio Materials","topic":"Calcium Carbonate Crystallization and Inhibition","field":"Materials Science","cited_by":12,"is_retracted":false,"has_abstract":true,"ca_institutions":"McGill University","funders":"Fonds de Recherche du Québec - Santé; Natural Sciences and Engineering Research Council of Canada; Canada Foundation for Innovation; National Natural Science Foundation of China; Canada Research Chairs; Ministry of Higher Education and Scientific Research","keywords":"Gypsum; Brushite; Cement; Calcium; Tartaric acid; Enantiomer; Toughness; Compressive strength; Materials science; Monoclinic crystal system; Chemical engineering; Calcium hydroxide; Chemistry; Composite material; Crystal structure; Organic chemistry; Metallurgy; Citric acid","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001482676,0.0002918082,0.000220163,0.0001660879,0.0001138484,0.0002337096,0.0001483198,0.0001761302,0.0005964871],"category_scores_gemma":[0.0002465206,0.0001344627,0.0002121761,0.0001193939,0.0002291575,0.0001609624,0.0001865485,0.0003707522,0.0001173138],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000197091,"about_ca_system_score_gemma":0.0002594208,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.000904607,"about_ca_topic_score_gemma":0.001502461,"domain_scores_codex":[0.9997919,0.00002863381,0.00002067449,0.00004162953,0.00007799258,0.00003931029],"domain_scores_gemma":[0.9998621,0.00002035558,0.00005416061,0.00001185588,0.00002441105,0.00002718475],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002888945,0.000005681302,0.0000666734,0.00001577948,0.00000170415,0.000007982001,0.000004421005,0.00002697931,0.9993356,0.00002074291,0.000007654417,0.0004779066],"study_design_scores_gemma":[0.000003838859,0.00005417375,0.0008794967,0.000001341396,0.000005005813,0.00001379587,0.000005686477,0.0002559096,0.9982389,0.000007374163,0.0005318325,0.00000262087],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.996714,0.00114667,0.00117429,0.00004581428,0.00001938708,0.00001477548,0.00007761126,0.00003359987,0.0007739895],"genre_scores_gemma":[0.9975592,0.0005881429,0.001255187,0.00003189522,0.000006021348,0.00001114686,0.00005173975,0.00001487909,0.0004816895],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.000904607,"threshold_uncertainty_score":0.001995444,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01221556772651215,"score_gpt":0.2187399265457836,"score_spread":0.2065243588192714,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}