{"id":"W3109891790","doi":"","title":"Anion-dependent C‒C Bond Cleavage of a Lignin Model within a Cationic Metal-organic Framework","year":2020,"lang":"en","type":"preprint","venue":"HAL (Le Centre pour la Communication Scientifique Directe)","topic":"Metal-Organic Frameworks: Synthesis and Applications","field":"Chemistry","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Ottawa","funders":"","keywords":"Cationic polymerization; Lignin; Bond cleavage; Cleavage (geology); Ion; Metal; Chemistry; Materials science; Organic chemistry; Catalysis; Composite material","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001188243,0.0002305032,0.0001296457,0.00009743655,0.0002144538,0.0002159715,0.000389824,0.0002579349,0.00206212],"category_scores_gemma":[0.0001641324,0.00006798023,0.0001232212,0.0001515714,0.0001392173,0.0002335728,0.0001867008,0.0004234244,0.0002356156],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002765974,"about_ca_system_score_gemma":0.000155965,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001672198,"about_ca_topic_score_gemma":0.001921646,"domain_scores_codex":[0.9999132,0.000008423657,0.000002296088,0.0000208628,0.00001877545,0.00003638324],"domain_scores_gemma":[0.9999387,0.00001580578,0.00001616752,0.000006903366,0.00000795792,0.00001438374],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0003406366,0.00006934227,0.0002275079,0.0001520657,0.00001203242,0.0002594985,0.0001169905,0.002120102,0.9914265,0.001493963,0.0003327483,0.003448694],"study_design_scores_gemma":[0.00003701962,0.0006758811,0.0008720802,0.00001097015,0.00001162336,0.00009509714,0.00006153827,0.007673099,0.9872607,0.0002847784,0.002997542,0.00001970371],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9947708,0.0003459722,0.001468685,0.00008044351,0.00002125597,0.00000985551,0.00006940023,0.00003273137,0.003200884],"genre_scores_gemma":[0.9982291,0.0001551598,0.000417509,0.0000130694,0.000003536859,0.00000323226,0.00005284865,0.000005473576,0.001120053],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.00206212,"threshold_uncertainty_score":0.006898463,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01886599676962469,"score_gpt":0.2353194320100327,"score_spread":0.2164534352404081,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}