{"id":"W3112165650","doi":"10.1039/d0qm00403k","title":"Physical supercritical fluid deposition of polymer films: controlling the crystallinity with pressure","year":2020,"lang":"en","type":"article","venue":"Materials Chemistry Frontiers","topic":"Phase Equilibria and Thermodynamics","field":"Engineering","cited_by":6,"is_retracted":false,"has_abstract":true,"ca_institutions":"Burnaby Hospital; Saskatoon Medical Imaging; University of Saskatchewan; Simon Fraser University","funders":"National Research Council Canada; Western Economic Diversification Canada; Canadian Institutes of Health Research; Natural Sciences and Engineering Research Council of Canada; Canada Research Chairs; University of Saskatchewan; Cummings Foundation","keywords":"Supercritical fluid; Tacticity; Crystallinity; Polymer; Materials science; Chemical engineering; Polypropylene; Deposition (geology); Polymer science; Pentane; Thermodynamics; Polymer chemistry; Composite material; Organic chemistry; Chemistry; Polymerization; Geology; Physics","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001124383,0.0002370808,0.0001663848,0.0001894275,0.0001930322,0.0002525513,0.0001691317,0.0001680457,0.000781254],"category_scores_gemma":[0.000294085,0.0001550844,0.0001144159,0.0001898428,0.0002656892,0.0003296828,0.0002017253,0.0004369015,0.0001380321],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0002457731,"about_ca_system_score_gemma":0.0001731354,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0009190977,"about_ca_topic_score_gemma":0.001676096,"domain_scores_codex":[0.999894,0.0000104521,0.000006148156,0.00002210479,0.00004257524,0.00002471663],"domain_scores_gemma":[0.9998748,0.000050639,0.00002975528,0.00001282809,0.00002030528,0.00001159472],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00002213501,0.000006386878,0.00004753402,0.00002327601,0.000001622577,0.0000147643,0.00002407658,0.00008923669,0.9988378,0.00006828755,0.00001728511,0.000847502],"study_design_scores_gemma":[0.000002507839,0.00002244663,0.0004109104,0.000001316788,0.000001290636,0.0000115152,0.000005498026,0.0004491971,0.9988245,0.00001022016,0.0002592864,0.000001255192],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9942307,0.000999227,0.001892806,0.00005663378,0.000013544,0.00002025268,0.0000727541,0.00003575344,0.002678394],"genre_scores_gemma":[0.996178,0.0007094159,0.001896243,0.00001699475,0.000008063782,0.00001337546,0.00005823969,0.00002448481,0.001095192],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0009190977,"threshold_uncertainty_score":0.002613604,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.004818571789443703,"score_gpt":0.1799461331646168,"score_spread":0.1751275613751731,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}