{"id":"W3113586550","doi":"10.1016/j.polymer.2020.123371","title":"Structural dependence of the molecular mobility in acetylated starch","year":2020,"lang":"en","type":"article","venue":"Polymer","topic":"Material Dynamics and Properties","field":"Materials Science","cited_by":10,"is_retracted":false,"has_abstract":false,"ca_institutions":"Western University; University of Waterloo","funders":"Ontario Ministry of Agriculture, Food and Rural Affairs","keywords":"Acetylation; Relaxation (psychology); Arrhenius equation; Fragility; Glass transition; Thermodynamics; Hydrogen bond; Chemistry; Atmospheric temperature range; Activation energy; Molecular dynamics; Materials science; Physical chemistry; Molecule; Computational chemistry; Organic chemistry; Physics; Biochemistry; Polymer","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00009830322,0.00006195516,0.0001034657,0.000008344917,0.00002435577,0.00001901371,0.0002730587,0.00002913505,0.0007103559],"category_scores_gemma":[0.00003510986,0.00003783199,0.0000260153,0.0001019517,0.0000832174,0.00005114656,0.0001470379,0.00005259853,0.00001205928],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.000008374904,"about_ca_system_score_gemma":0.00003212572,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001011502,"about_ca_topic_score_gemma":0.00004174683,"domain_scores_codex":[0.999339,0.000082485,0.000162571,0.0001404183,0.000147236,0.0001282726],"domain_scores_gemma":[0.9997284,0.000009909142,0.00004351134,0.0001683583,0.00001890934,0.00003085447],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00005661363,0.00000439485,0.00221786,0.00002531367,0.000001199688,0.000001087619,0.0004876579,0.00009429835,0.996158,0.0008320776,0.000001655343,0.0001198368],"study_design_scores_gemma":[0.0001026423,0.00002777233,0.007261047,0.000008093688,0.000002228583,6.728985e-7,0.00003150943,0.002163115,0.9901284,0.0002078301,0.00001299928,0.00005368841],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9985656,0.0002785989,0.00001182221,0.0006836005,0.0001485376,0.0001018803,0.00002566956,0.00001104831,0.0001732329],"genre_scores_gemma":[0.99968,0.00000191203,0.00004408432,0.0002318867,0.00001077335,0.000003538576,7.966677e-7,0.00000501678,0.00002194298],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.006029604,"threshold_uncertainty_score":0.7777898,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01795459563593179,"score_gpt":0.2332925942396342,"score_spread":0.2153379986037024,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}