{"id":"W3116202513","doi":"10.1021/acs.jpcb.0c10074","title":"Fully Conjugated Pyrene–BODIPY and Pyrene–BODIPY–Ferrocene Dyads and Triads: Synthesis, Characterization, and Selective Noncovalent Interactions with Nanocarbon Materials","year":2020,"lang":"en","type":"article","venue":"The Journal of Physical Chemistry B","topic":"Luminescence and Fluorescent Materials","field":"Materials Science","cited_by":21,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Manitoba","funders":"Division of Chemistry; Natural Sciences and Engineering Research Council of Canada; Canada Foundation for Innovation; University of Tennessee; Western Canada Research Grid; University of Manitoba; Minnesota Supercomputing Institute, University of Minnesota","keywords":"BODIPY; Chemistry; Photochemistry; Pyrene; Conjugated system; Cyclic voltammetry; Fullerene; Ferrocene; Fluorescence spectroscopy; Ultrafast laser spectroscopy; Spectroscopy; Fluorescence; Organic chemistry; Electrochemistry; Physical chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0002494545,0.0003785742,0.000316045,0.0001859101,0.0001301803,0.0002799234,0.0002345771,0.0003144509,0.0007107574],"category_scores_gemma":[0.0002772112,0.0001810523,0.0001893283,0.0001710808,0.0002294866,0.0003052965,0.0002328351,0.0003892591,0.0002587203],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0004539969,"about_ca_system_score_gemma":0.0001491226,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0003658808,"about_ca_topic_score_gemma":0.0006719992,"domain_scores_codex":[0.999756,0.00003586183,0.00001901448,0.00006956302,0.00006662731,0.0000528315],"domain_scores_gemma":[0.9997863,0.00005172961,0.00004003874,0.00003327979,0.00003345196,0.00005515986],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00004220357,0.00001268735,0.00007014874,0.00001722722,0.000004917086,0.00001602637,0.00000864609,0.00006487543,0.9992889,0.00003838409,0.00001061241,0.0004253245],"study_design_scores_gemma":[0.000005638249,0.000134585,0.0006122083,0.000001166448,0.000007984853,0.00007232778,0.00000520919,0.0003787981,0.9983807,0.000008843621,0.0003897935,0.000002812641],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9952543,0.0006599287,0.003371528,0.00002756619,0.00001067619,0.00003077179,0.0001087101,0.00003868011,0.0004978242],"genre_scores_gemma":[0.9927611,0.0004513286,0.004809553,0.00003261671,0.000006516061,0.00004511093,0.0002634761,0.00002281532,0.001607487],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.0007107574,"threshold_uncertainty_score":0.003293991,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.009902680290548646,"score_gpt":0.222534695371214,"score_spread":0.2126320150806653,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}