{"id":"W3117141022","doi":"10.3329/bjsir.v55i4.50961","title":"Fluxional dynamics of terpyridine ligand in [Ru(bpy-d8)2(η2-tpy)]2+ complex","year":2020,"lang":"en","type":"article","venue":"Bangladesh Journal of Scientific and Industrial Research","topic":"Metal complexes synthesis and properties","field":"Medicine","cited_by":0,"is_retracted":false,"has_abstract":true,"ca_institutions":"","funders":"Memorial University of Newfoundland","keywords":"Terpyridine; Chemistry; Trifluoroacetic acid; Protonation; Ring (chemistry); Ligand (biochemistry); Pyridine; Methanol; Medicinal chemistry; Stereochemistry; Metal; Organic chemistry; Ion","routes":{"ca_aff":false,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":true},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.004448155,0.0001277806,0.0005785108,0.0005829241,0.0001644395,0.0001467386,0.0002951302,0.0001416056,0.000499398],"category_scores_gemma":[0.002082692,0.00009088444,0.0001264928,0.00102923,0.0008055551,0.000189415,0.000164617,0.0009730571,0.00001060152],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.00008241086,"about_ca_system_score_gemma":0.0005909941,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0000381748,"about_ca_topic_score_gemma":0.00001325756,"domain_scores_codex":[0.9968398,0.0002926722,0.0008214369,0.0002580075,0.001421842,0.000366269],"domain_scores_gemma":[0.9981624,0.0003176602,0.0002186231,0.0001598665,0.0007526707,0.0003887067],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.007003529,0.0006259696,0.04336735,0.0003414197,0.000179867,0.0002061774,0.001445361,0.00001821696,0.8282652,0.002705897,0.04677934,0.06906169],"study_design_scores_gemma":[0.03864638,0.01956876,0.1426539,0.006159801,0.0004346186,0.001493172,0.01237029,0.03405771,0.4328183,0.004854334,0.3055207,0.001422026],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9896722,0.0006943836,0.00003205517,0.007511474,0.0002427822,0.000260494,0.00004070753,0.000003301661,0.001542633],"genre_scores_gemma":[0.9983287,0.00008732012,0.0002581337,0.00005215576,0.0005071217,0.000001682164,0.00001916328,0.00001311469,0.0007326383],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.3954468,"threshold_uncertainty_score":0.5468059,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.3998350979668211,"score_gpt":0.3833401816024079,"score_spread":0.01649491636441319,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}