{"id":"W3118360940","doi":"10.1002/aic.17154","title":"Unraveling the cooperative effects of acid sites and kinetics for pyrolysis of <scp>CHF<sub>3</sub></scp> to <scp>C<sub>2</sub>F<sub>4</sub></scp> and <scp>C<sub>3</sub>F<sub>6</sub></scp> on <scp>SO<sub>4</sub><sup>2</sup></scp><sup>−</sup>/<scp>ZrO<sub>2</sub>‐SiO<sub>2</sub></scp>","year":2021,"lang":"en","type":"article","venue":"AIChE Journal","topic":"Inorganic Fluorides and Related Compounds","field":"Chemistry","cited_by":5,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"","keywords":"Lewis acids and bases; Decomposition; Catalysis; Chemistry; Pyrolysis; Kinetics; Brønsted–Lowry acid–base theory; Selectivity; Lewis number; Phase (matter); Hexafluoropropylene; Tetrafluoroethylene; Chemical engineering; Physical chemistry; Polymer; Organic chemistry","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.0001043951,0.0002311115,0.0001539483,0.0001096601,0.00009435539,0.0001226207,0.0001237843,0.0002000434,0.000718126],"category_scores_gemma":[0.0001442398,0.0001353467,0.0001902803,0.00009173451,0.0001456394,0.0002308833,0.00009528026,0.0002895393,0.0001079993],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001358979,"about_ca_system_score_gemma":0.0001529966,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.001353852,"about_ca_topic_score_gemma":0.002583046,"domain_scores_codex":[0.999945,0.000004802436,0.000002826315,0.0000121629,0.00002220171,0.00001290007],"domain_scores_gemma":[0.9999536,0.00001418138,0.00001300282,0.000004637706,0.000009023541,0.000005505322],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00007180982,0.000007678906,0.0005890829,0.00003794096,0.000006252684,0.00002890313,0.00002392395,0.0002648111,0.9974764,0.00004015578,0.00001720887,0.001435708],"study_design_scores_gemma":[0.000003175883,0.000129746,0.004677116,0.000002718524,0.0000116251,0.0000453335,0.00003884594,0.002014233,0.9926577,0.00002389603,0.0003903479,0.000005180041],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9984717,0.0002676557,0.0008060166,0.00001463556,0.000003238677,0.000005349335,0.00005497234,0.00001501882,0.0003613185],"genre_scores_gemma":[0.9987992,0.0002353392,0.00066752,0.000004812337,0.000001175592,0.000004720348,0.00004955663,0.000004401334,0.0002331546],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.001353852,"threshold_uncertainty_score":0.002691984,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.00841259267119704,"score_gpt":0.2151609399270152,"score_spread":0.2067483472558182,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}