{"id":"W3118953212","doi":"10.1039/d0cc07736d","title":"Oxyphosphoranes as precursors to bridging phosphate-catecholate ligands","year":2021,"lang":"en","type":"article","venue":"Chemical Communications","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":9,"is_retracted":false,"has_abstract":true,"ca_institutions":"University of Toronto","funders":"Natural Science Foundation of Ningbo; Southern University of Science and Technology; National Natural Science Foundation of China","keywords":"Bimetallic strip; Bridging (networking); Halide; Chemistry; Chelation; Phosphate; Metal; Combinatorial chemistry; Polymer chemistry; Inorganic chemistry; Organic chemistry; Computer science","routes":{"ca_aff":true,"ca_fund":false,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"codex-gemma-dda1882f352a","candidate_categories":["insufficient_payload"],"consensus_categories":[],"category_scores_codex":[0.0001231887,0.0001681704,0.0002207701,0.0000678383,0.0002272774,0.00009370402,0.001092645,0.0001395799,0.0009299964],"category_scores_gemma":[0.0006911703,0.0001892225,0.0001555287,0.001151943,0.00008610012,0.000101681,0.0006996931,0.0003571325,0.0006580832],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0001116235,"about_ca_system_score_gemma":0.00009293404,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.00004545578,"about_ca_topic_score_gemma":0.000006756321,"domain_scores_codex":[0.9987947,0.000015463,0.0003417688,0.000332452,0.0002499481,0.0002656376],"domain_scores_gemma":[0.9971493,0.0001882333,0.00008311609,0.002073458,0.0002419637,0.0002639651],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.00001605555,0.0003656525,0.0005665482,0.00003995057,0.0001479495,0.00000945717,0.001134848,0.00001748189,0.9614679,0.001920709,0.002628807,0.03168465],"study_design_scores_gemma":[0.0002094751,0.000002472237,0.00001620252,0.00003504366,0.00005129685,0.00001859143,0.0003455198,0.0005084895,0.9200321,0.0002874453,0.07827692,0.0002164638],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.8551878,0.003824101,0.0002685564,0.007538146,0.0000430826,0.00008027813,0.00003639451,0.0003583246,0.1326633],"genre_scores_gemma":[0.9911711,0.0004167609,0.001768196,0.0008170977,0.00003930342,0.00008294439,0.0004612957,0.00003215713,0.00521112],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.1359833,"threshold_uncertainty_score":0.9999833,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01962283133832168,"score_gpt":0.2834014064324208,"score_spread":0.2637785750940991,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}