{"id":"W3119442382","doi":"10.1039/d0sc06518h","title":"Reversible Pt<sup>II</sup>–CH<sub>3</sub> deuteration without methane loss: metal–ligand cooperation <i>vs.</i> ligand-assisted Pt<sup>II</sup>-protonation","year":2021,"lang":"en","type":"article","venue":"Chemical Science","topic":"Asymmetric Hydrogenation and Catalysis","field":"Chemistry","cited_by":8,"is_retracted":false,"has_abstract":true,"ca_institutions":"Vancouver Biotech (Canada); University of British Columbia","funders":"Japan Society for the Promotion of Science; American Chemical Society Petroleum Research Fund; Okinawa Institute of Science and Technology Graduate University; Natural Sciences and Engineering Research Council of Canada; Universidade Federal de São João del-Rei; University of British Columbia","keywords":"Ligand (biochemistry); Chemistry; Protonation; Yield (engineering); Metal; Methane; Group 2 organometallic chemistry; Crystallography; Medicinal chemistry; Stereochemistry; Molecule; Physics; Ion; Organic chemistry","routes":{"ca_aff":true,"ca_fund":true,"ca_venue":false,"about_ca":false,"invisible_to_affiliation_only":false},"retraction":null,"screen":null,"direct_labels":[],"prediction":{"model_version":"metacan-v3-hybrid-931329e0061c","candidate_categories":[],"consensus_categories":[],"category_scores_codex":[0.00006810318,0.0002812972,0.0001502608,0.00005271191,0.0001544943,0.0002052614,0.0002874542,0.0002234892,0.002502054],"category_scores_gemma":[0.0001469078,0.000156049,0.00008563721,0.00011869,0.0002453466,0.000271265,0.0002426922,0.0003294949,0.0004317012],"about_ca_system_candidate":false,"about_ca_system_consensus":false,"about_ca_system_score_codex":0.0003471136,"about_ca_system_score_gemma":0.0001849374,"about_ca_topic_candidate":false,"about_ca_topic_consensus":false,"about_ca_topic_score_codex":0.0007884007,"about_ca_topic_score_gemma":0.001677223,"domain_scores_codex":[0.9999175,0.000005665819,0.000003795108,0.00002651079,0.00001814889,0.00002843075],"domain_scores_gemma":[0.9999677,0.000006374631,0.000009847484,0.000006122232,0.000004067705,0.00000586569],"domain_codex":null,"domain_gemma":null,"domain_candidate":null,"domain_consensus":null,"study_design_codex":"bench_or_experimental","study_design_gemma":"bench_or_experimental","study_design_scores_codex":[0.0002194937,0.000009851399,0.0001518722,0.00007920455,0.000006030752,0.00007647531,0.00005079364,0.0001094914,0.9964414,0.0003239687,0.0003091349,0.002222158],"study_design_scores_gemma":[0.000007053344,0.00003629399,0.0002617834,0.000001441238,0.000002244687,0.00005788673,0.00001465391,0.0002362241,0.9978209,0.00001968635,0.001539684,0.000002264088],"study_design_candidate":"bench_or_experimental","study_design_consensus":"bench_or_experimental","genre_codex":"empirical","genre_gemma":"empirical","genre_scores_codex":[0.9837602,0.0007215985,0.004669679,0.0001557038,0.00006994249,0.00003370786,0.0004039864,0.0002688534,0.009916285],"genre_scores_gemma":[0.9965948,0.0002249009,0.0008214135,0.0000297169,0.00000340789,0.0000105138,0.0001446004,0.00002444945,0.002146238],"genre_candidate":"empirical","genre_consensus":"empirical","teacher_disagreement_score":0.002502054,"threshold_uncertainty_score":0.008370221,"prediction_status":"machine_predicted_unvalidated"},"machine_scores":{"provisional":true,"baseline":true,"maturity_gate_passed":false,"score_opus":0.01399688110623413,"score_gpt":0.2459988578016163,"score_spread":0.2320019766953822,"validation_status":"score_only:v0-immature-baseline","note":"Baseline scores from an immature model (maturity gate not passed). Scores rank; they never assert a category."}}